, volume 60 , issue 37 , pages 150938

Nondissociative chain walking as a strategy in catalytic organic synthesis

Takuya Kochi ¹

Shota KANNO ¹

Fumitoshi Kakiuchi ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

Department of Chemistry, Faculty of Science and Technology, Keio University, 3‐14‐1, Hiyoshi, Kohoku‐ku, Yokohama, 223‐8522 (Japan) |

Publication type: Journal Article

Publication date: 2019-09-01

Elsevier

Tetrahedron Letters

scimago Q3

wos Q3

SJR: 0.334

CiteScore: 3.2

Impact factor: 1.5

ISSN: 00404039, 18733581

DOI: 10.1016/j.tetlet.2019.07.029

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Organic Chemistry

Drug Discovery

Biochemistry

Abstract

“Nondissociative” chain walking is a mechanism where an alkylmetal species undergoes rapid β-hydride elimination and reinsertion to move the metal center along the alkyl chain without dissociating an alkene intermediate during the migration process. This digest summarizes the unique characteristics of the nondissociative chain walking mechanism compared to the stepwise alkene isomerization mechanism and their use in catalytic organic synthesis.

Found

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Tikhomirov Alexander

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DSc in Chemistry, associate professor

60 publications, 931 citations

h-index: 17

Mendeleev University of Chemical Technology of Russia

Gause Institute of New Antibiotics

Research interests

Medicinal Chemistry

1 citation

Litvinova Valeriya

PhD in Chemistry

13 publications, 98 citations

h-index: 5

Gause Institute of New Antibiotics

Research interests

Antibiotics

Organic synthesis

Synthesis of biologically active substances

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Kochi T., KANNO S., Kakiuchi F. Nondissociative chain walking as a strategy in catalytic organic synthesis // Tetrahedron Letters. 2019. Vol. 60. No. 37. p. 150938.

GOST all authors (up to 50) Copy

Kochi T., KANNO S., Kakiuchi F. Nondissociative chain walking as a strategy in catalytic organic synthesis // Tetrahedron Letters. 2019. Vol. 60. No. 37. p. 150938.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.tetlet.2019.07.029

UR - https://doi.org/10.1016/j.tetlet.2019.07.029

TI - Nondissociative chain walking as a strategy in catalytic organic synthesis

T2 - Tetrahedron Letters

AU - Kochi, Takuya

AU - KANNO, Shota

AU - Kakiuchi, Fumitoshi

PY - 2019

DA - 2019/09/01

PB - Elsevier

SP - 150938

IS - 37

VL - 60

SN - 0040-4039

SN - 1873-3581

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2019_Kochi,

author = {Takuya Kochi and Shota KANNO and Fumitoshi Kakiuchi},

title = {Nondissociative chain walking as a strategy in catalytic organic synthesis},

journal = {Tetrahedron Letters},

year = {2019},

volume = {60},

publisher = {Elsevier},

month = {sep},

url = {https://doi.org/10.1016/j.tetlet.2019.07.029},

number = {37},

pages = {150938},

doi = {10.1016/j.tetlet.2019.07.029}

}

MLA

Cite this

MLA Copy

Kochi, Takuya, et al. “Nondissociative chain walking as a strategy in catalytic organic synthesis.” Tetrahedron Letters, vol. 60, no. 37, Sep. 2019, p. 150938. https://doi.org/10.1016/j.tetlet.2019.07.029.

Publisher

Elsevier

Journal

Tetrahedron Letters

scimago Q3

wos Q3

SJR

0.334

CiteScore

3.2

Impact factor

1.5

ISSN

00404039 (Print)

18733581 (Electronic)