Aminofunctional linear low density polyethylene via metallocene-catalysed ethene copolymerization with N,N-bis(trimethylsilyl)-1-amino-10-undecene
Publication type: Journal Article
Publication date: 1997-05-01
scimago Q1
wos Q2
SJR: 0.843
CiteScore: 7.7
Impact factor: 4.5
ISSN: 00323861, 18732291
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Abstract
Ethene was copolymerized with N,N-bis(trimethylsilyl)-1-amino-10-undecene in the presence of homogeneous, MAO-activated rac-Me2Si(Benz[e]Ind)2ZrCl2 to yield, upon hydrolysis of the silylated amines, short chain branched linear low density polyethylene (LLDPE) with pendent aminoalkyl groups. Aminofunctional LLDPEs were characterized by means of 1H-n.m.r. FTi.r., elemental analysis and thermal analysis (d.s.c.). Amine functionality, varying between 6 and 19wt% 1-amino-10-undecene incorporation, influenced significantly the characteristics of LLDPE. Such aminofunctional LLDPEs were applied as reactive intermediates in reactive processing. FTi.r. analysis was applied to monitor the imidecoupling reaction of poly(ethene-co-aminoundecene) with poly(styrene-alt-maleic anhydride).
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71
Total citations:
71
Citations from 2024:
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(7%)
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GOST
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Schneider M. J. et al. Aminofunctional linear low density polyethylene via metallocene-catalysed ethene copolymerization with N,N-bis(trimethylsilyl)-1-amino-10-undecene // Polymer. 1997. Vol. 38. No. 10. pp. 2455-2459.
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Schneider M. J., Schäfer R., Mülhaupt R. Aminofunctional linear low density polyethylene via metallocene-catalysed ethene copolymerization with N,N-bis(trimethylsilyl)-1-amino-10-undecene // Polymer. 1997. Vol. 38. No. 10. pp. 2455-2459.
Cite this
RIS
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TY - JOUR
DO - 10.1016/S0032-3861(96)00785-9
UR - https://doi.org/10.1016/S0032-3861(96)00785-9
TI - Aminofunctional linear low density polyethylene via metallocene-catalysed ethene copolymerization with N,N-bis(trimethylsilyl)-1-amino-10-undecene
T2 - Polymer
AU - Schneider, Martin Julius
AU - Schäfer, Rüdiger
AU - Mülhaupt, Rolf
PY - 1997
DA - 1997/05/01
PB - Elsevier
SP - 2455-2459
IS - 10
VL - 38
SN - 0032-3861
SN - 1873-2291
ER -
Cite this
BibTex (up to 50 authors)
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@article{1997_Schneider,
author = {Martin Julius Schneider and Rüdiger Schäfer and Rolf Mülhaupt},
title = {Aminofunctional linear low density polyethylene via metallocene-catalysed ethene copolymerization with N,N-bis(trimethylsilyl)-1-amino-10-undecene},
journal = {Polymer},
year = {1997},
volume = {38},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016/S0032-3861(96)00785-9},
number = {10},
pages = {2455--2459},
doi = {10.1016/S0032-3861(96)00785-9}
}
Cite this
MLA
Copy
Schneider, Martin Julius, et al. “Aminofunctional linear low density polyethylene via metallocene-catalysed ethene copolymerization with N,N-bis(trimethylsilyl)-1-amino-10-undecene.” Polymer, vol. 38, no. 10, May. 1997, pp. 2455-2459. https://doi.org/10.1016/S0032-3861(96)00785-9.