Chemical Reviews, volume 115, issue 22, pages 12286-12319

Topological Motifs in Cyanometallates: From Building Units to Three-Periodic Frameworks

Publication typeJournal Article
Publication date2015-10-27
Journal: Chemical Reviews
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor62.1
ISSN00092665, 15206890
General Chemistry
Abstract
This review focuses on topological features of three-periodic (framework) p, d, and f metal cyano complexes or cyanometallates, i.e. coordination compounds, where CN(-) ligands play the main structure-forming role. In addition, molecular, one-periodic (chain), and two-periodic (layer) cyanometallates are considered as possible building blocks of the three-periodic cyanometallates. All cyanometallates are treated as systems of nodes (mononuclear, polynuclear, or transitional metal cluster complexes) joined together via CN-containing spacers. The most typical nodes and spacers as well as methods of their connection are described and systematized. Particular attention is paid to the overall structural motifs in the three-periodic cyanometallates, especially to the relations between the local coordination (coordination figure) of structural units and the entire framework topology. The chemical factors are discussed that influence the cyanometallate topological properties due to modification of nodes, spacers, or coordination figures.

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Alexandrov E. V. et al. Topological Motifs in Cyanometallates: From Building Units to Three-Periodic Frameworks // Chemical Reviews. 2015. Vol. 115. No. 22. pp. 12286-12319.
GOST all authors (up to 50) Copy
Alexandrov E. V., Virovets A., Blatov V. A., Peresypkina E. V. Topological Motifs in Cyanometallates: From Building Units to Three-Periodic Frameworks // Chemical Reviews. 2015. Vol. 115. No. 22. pp. 12286-12319.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acs.chemrev.5b00320
UR - https://doi.org/10.1021%2Facs.chemrev.5b00320
TI - Topological Motifs in Cyanometallates: From Building Units to Three-Periodic Frameworks
T2 - Chemical Reviews
AU - Alexandrov, Eugeny V.
AU - Virovets, Alexander
AU - Blatov, Vladislav A.
AU - Peresypkina, Eugenia V.
PY - 2015
DA - 2015/10/27 00:00:00
PB - American Chemical Society (ACS)
SP - 12286-12319
IS - 22
VL - 115
SN - 0009-2665
SN - 1520-6890
ER -
BibTex |
Cite this
BibTex Copy
@article{2015_Alexandrov,
author = {Eugeny V. Alexandrov and Alexander Virovets and Vladislav A. Blatov and Eugenia V. Peresypkina},
title = {Topological Motifs in Cyanometallates: From Building Units to Three-Periodic Frameworks},
journal = {Chemical Reviews},
year = {2015},
volume = {115},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021%2Facs.chemrev.5b00320},
number = {22},
pages = {12286--12319},
doi = {10.1021/acs.chemrev.5b00320}
}
MLA
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Alexandrov, Eugeny V., et al. “Topological Motifs in Cyanometallates: From Building Units to Three-Periodic Frameworks.” Chemical Reviews, vol. 115, no. 22, Oct. 2015, pp. 12286-12319. https://doi.org/10.1021%2Facs.chemrev.5b00320.
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