Self-Assembly of Lanthanide-Covalent Organic Polyhedra: Chameleonic Luminescence and Efficient Catalysis
Shi Long Han
1, 2
,
Jian Yang
2
,
Debakanta Tripathy
2
,
Xiao-Qing Guo
2, 3
,
Shao-jun Hu
2, 3
,
Xiaopeng Li
2
,
Li-Xuan Cai
2
,
Li‐Peng Zhou
2
,
Qing‐Fu Sun
1, 2, 3
Publication type: Journal Article
Publication date: 2020-09-22
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
32960581
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
A series of multinuclear lanthanide-covalent organic polyhedra (LnCOPs), including pillar-typed triangular prisms 1-Ln3 and tetrahedra 2-Ln4 (Ln = LaIII, SmIII, EuIII), have been constructed for the first time, through either one-pot subcomponent self-assembly or postassembly metalation. In contrast to the known tetrahedral cages based on transition metals, the pillar-typed polyhedra were favored from the same organic components in the presence of lanthanides. Besides this, facile transmetalations between the 1-Ln3 polyhedra endow cascade chameleonic luminescence. Meanwhile, the open metal sites and pendent amine groups on 1-Ln3 enable these polyhedra to catalyze the Henry reaction efficiently.
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Total citations:
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Citations from 2024:
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(37.5%)
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GOST
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Han S. L. et al. Self-Assembly of Lanthanide-Covalent Organic Polyhedra: Chameleonic Luminescence and Efficient Catalysis // Inorganic Chemistry. 2020. Vol. 59. No. 19. pp. 14023-14030.
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Han S. L., Yang J., Tripathy D., Guo X., Hu S., Li X., Cai L., Zhou L., Sun Q. Self-Assembly of Lanthanide-Covalent Organic Polyhedra: Chameleonic Luminescence and Efficient Catalysis // Inorganic Chemistry. 2020. Vol. 59. No. 19. pp. 14023-14030.
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RIS
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TY - JOUR
DO - 10.1021/acs.inorgchem.0c01780
UR - https://doi.org/10.1021/acs.inorgchem.0c01780
TI - Self-Assembly of Lanthanide-Covalent Organic Polyhedra: Chameleonic Luminescence and Efficient Catalysis
T2 - Inorganic Chemistry
AU - Han, Shi Long
AU - Yang, Jian
AU - Tripathy, Debakanta
AU - Guo, Xiao-Qing
AU - Hu, Shao-jun
AU - Li, Xiaopeng
AU - Cai, Li-Xuan
AU - Zhou, Li‐Peng
AU - Sun, Qing‐Fu
PY - 2020
DA - 2020/09/22
PB - American Chemical Society (ACS)
SP - 14023-14030
IS - 19
VL - 59
PMID - 32960581
SN - 0020-1669
SN - 1520-510X
ER -
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BibTex (up to 50 authors)
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@article{2020_Han,
author = {Shi Long Han and Jian Yang and Debakanta Tripathy and Xiao-Qing Guo and Shao-jun Hu and Xiaopeng Li and Li-Xuan Cai and Li‐Peng Zhou and Qing‐Fu Sun},
title = {Self-Assembly of Lanthanide-Covalent Organic Polyhedra: Chameleonic Luminescence and Efficient Catalysis},
journal = {Inorganic Chemistry},
year = {2020},
volume = {59},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/acs.inorgchem.0c01780},
number = {19},
pages = {14023--14030},
doi = {10.1021/acs.inorgchem.0c01780}
}
Cite this
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Han, Shi Long, et al. “Self-Assembly of Lanthanide-Covalent Organic Polyhedra: Chameleonic Luminescence and Efficient Catalysis.” Inorganic Chemistry, vol. 59, no. 19, Sep. 2020, pp. 14023-14030. https://doi.org/10.1021/acs.inorgchem.0c01780.