Cyclic (Alkyl)(amino)carbenes: Synthesis of Iminium Precursors and Structural Properties
François Vermersch
1
,
Luana Oliveira
1
,
Joseph Hunter
1
,
Michèle Soleilhavoup
1
,
Rodolphe Jazzar
1
,
Publication type: Journal Article
Publication date: 2022-02-08
scimago Q2
wos Q1
SJR: 0.737
CiteScore: 6.1
Impact factor: 3.6
ISSN: 00223263, 15206904
PubMed ID:
35133152
Organic Chemistry
Abstract
Using readily available preallylated aldehydes, we report a simple and divergent synthesis of cyclic (alkyl)(amino)carbene (CAAC) iminium precursors. Using a combination of crystallographic data and steric maps, we further elaborate on the specific steric properties of CAAC ligands with respect to state-of-the-art phosphine and carbene ligands.
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Metrics
41
Total citations:
41
Citations from 2024:
22
(53.66%)
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GOST
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Vermersch F. et al. Cyclic (Alkyl)(amino)carbenes: Synthesis of Iminium Precursors and Structural Properties // Journal of Organic Chemistry. 2022. Vol. 87. No. 5. pp. 3511-3518.
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Vermersch F., Oliveira L., Hunter J., Soleilhavoup M., Jazzar R., Bertrand G. Cyclic (Alkyl)(amino)carbenes: Synthesis of Iminium Precursors and Structural Properties // Journal of Organic Chemistry. 2022. Vol. 87. No. 5. pp. 3511-3518.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.joc.1c03075
UR - https://doi.org/10.1021/acs.joc.1c03075
TI - Cyclic (Alkyl)(amino)carbenes: Synthesis of Iminium Precursors and Structural Properties
T2 - Journal of Organic Chemistry
AU - Vermersch, François
AU - Oliveira, Luana
AU - Hunter, Joseph
AU - Soleilhavoup, Michèle
AU - Jazzar, Rodolphe
AU - Bertrand, Gilles
PY - 2022
DA - 2022/02/08
PB - American Chemical Society (ACS)
SP - 3511-3518
IS - 5
VL - 87
PMID - 35133152
SN - 0022-3263
SN - 1520-6904
ER -
Cite this
BibTex (up to 50 authors)
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@article{2022_Vermersch,
author = {François Vermersch and Luana Oliveira and Joseph Hunter and Michèle Soleilhavoup and Rodolphe Jazzar and Gilles Bertrand},
title = {Cyclic (Alkyl)(amino)carbenes: Synthesis of Iminium Precursors and Structural Properties},
journal = {Journal of Organic Chemistry},
year = {2022},
volume = {87},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/acs.joc.1c03075},
number = {5},
pages = {3511--3518},
doi = {10.1021/acs.joc.1c03075}
}
Cite this
MLA
Copy
Vermersch, François, et al. “Cyclic (Alkyl)(amino)carbenes: Synthesis of Iminium Precursors and Structural Properties.” Journal of Organic Chemistry, vol. 87, no. 5, Feb. 2022, pp. 3511-3518. https://doi.org/10.1021/acs.joc.1c03075.