Journal of Organic Chemistry, volume 88, issue 15, pages 11003-11009

Construction of Annulated Spiro[4.4]-nonane-diones via the Tandem [4 + 2]-Cycloaddition/Aromatization Reaction

Publication typeJournal Article
Publication date2023-07-18
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor3.6
ISSN00223263, 15206904
Organic Chemistry
Abstract
A method for the synthesis of both symmetric and asymmetric fused spiro[4.4]-nonane-dione derivatives has been developed. It is based on a Diels–Alder reaction of spiro[4.4]nona-2,7-diene-1,6-dione as a dienophile component followed by immediate aromatization of the adduct. An active diene component can be generated using the tetrabromoxylene/NaI system, the 1,3-diphenylisobenzofuran/BF3 system, or substituted cyclones.

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Ivanov K. S. et al. Construction of Annulated Spiro[4.4]-nonane-diones via the Tandem [4 + 2]-Cycloaddition/Aromatization Reaction // Journal of Organic Chemistry. 2023. Vol. 88. No. 15. pp. 11003-11009.
GOST all authors (up to 50) Copy
Ivanov K. S., Samburskiy D. E., Zargarova L. V., Komarov V. Y., Mostovich E. A. Construction of Annulated Spiro[4.4]-nonane-diones via the Tandem [4 + 2]-Cycloaddition/Aromatization Reaction // Journal of Organic Chemistry. 2023. Vol. 88. No. 15. pp. 11003-11009.
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RIS Copy
TY - JOUR
DO - 10.1021/acs.joc.3c00981
UR - https://doi.org/10.1021%2Facs.joc.3c00981
TI - Construction of Annulated Spiro[4.4]-nonane-diones via the Tandem [4 + 2]-Cycloaddition/Aromatization Reaction
T2 - Journal of Organic Chemistry
AU - Ivanov, Konstantin S
AU - Samburskiy, Denis E.
AU - Zargarova, Leila V
AU - Komarov, Vladislav Yu.
AU - Mostovich, Evgeny A.
PY - 2023
DA - 2023/07/18 00:00:00
PB - American Chemical Society (ACS)
SP - 11003-11009
IS - 15
VL - 88
SN - 0022-3263
SN - 1520-6904
ER -
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@article{2023_Ivanov,
author = {Konstantin S Ivanov and Denis E. Samburskiy and Leila V Zargarova and Vladislav Yu. Komarov and Evgeny A. Mostovich},
title = {Construction of Annulated Spiro[4.4]-nonane-diones via the Tandem [4 + 2]-Cycloaddition/Aromatization Reaction},
journal = {Journal of Organic Chemistry},
year = {2023},
volume = {88},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021%2Facs.joc.3c00981},
number = {15},
pages = {11003--11009},
doi = {10.1021/acs.joc.3c00981}
}
MLA
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Ivanov, Konstantin S., et al. “Construction of Annulated Spiro[4.4]-nonane-diones via the Tandem [4 + 2]-Cycloaddition/Aromatization Reaction.” Journal of Organic Chemistry, vol. 88, no. 15, Jul. 2023, pp. 11003-11009. https://doi.org/10.1021%2Facs.joc.3c00981.
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