Journal of Physical Chemistry Letters, volume 8, issue 6, pages 1211-1218
Probing the Intrinsic Thermal and Photochemical Stability of Hybrid and Inorganic Lead Halide Perovskites.
Akbulatov Azat F
1
,
Luchkin Sergey
2
,
Dremova Nadezhda N
1
,
Gerasimov Kirill L
3
,
ZHIDKOV I. S.
4
,
Anokhin Denis V.
1, 3
,
Kurmaev E. Z.
4, 5
,
Troshin Pavel A.
1, 2
Publication type: Journal Article
Publication date: 2017-03-02
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 5.7
ISSN: 19487185
Physical and Theoretical Chemistry
General Materials Science
Abstract
We report a careful and systematic study of thermal and photochemical degradation of a series of complex haloplumbates APbX3 (X = I, Br) with hybrid organic (A+ = CH3NH3) and inorganic (A+ = Cs+) cations under anoxic conditions (i.e., without exposure to oxygen and moisture by testing in an inert glovebox environment). We show that the most common hybrid materials (e.g., MAPbI3) are intrinsically unstable with respect to the heat- and light-induced stress and, therefore, can hardly sustain the real solar cell operation conditions. On the contrary, the cesium-based all-inorganic complex lead halides revealed far superior stability and, therefore, provide an impetus for creation of highly efficient and stable perovskite solar cells that can potentially achieve pragmatic operational benchmarks.
Citations by journals
|
2
4
6
8
10
12
14
|
|
|
Journal of Physical Chemistry Letters
|
Journal of Physical Chemistry Letters
13 publications, 6.07%
|
|
ACS applied materials & interfaces
|
ACS applied materials & interfaces
11 publications, 5.14%
|
|
ACS Applied Energy Materials
|
ACS Applied Energy Materials
10 publications, 4.67%
|
|
Journal of Physical Chemistry C
|
Journal of Physical Chemistry C
8 publications, 3.74%
|
|
Advanced Energy Materials
|
Advanced Energy Materials
8 publications, 3.74%
|
|
Solar RRL
|
Solar RRL
8 publications, 3.74%
|
|
Nano Energy
|
Nano Energy
7 publications, 3.27%
|
|
Journal of Materials Chemistry A
|
Journal of Materials Chemistry A
6 publications, 2.8%
|
|
Advanced Functional Materials
|
Advanced Functional Materials
6 publications, 2.8%
|
|
Sustainable Energy and Fuels
|
Sustainable Energy and Fuels
5 publications, 2.34%
|
|
Solar Energy
|
Solar Energy
5 publications, 2.34%
|
|
Solar Energy Materials and Solar Cells
|
Solar Energy Materials and Solar Cells
4 publications, 1.87%
|
|
Nanomaterials
|
Nanomaterials
4 publications, 1.87%
|
|
Advanced Materials
|
Advanced Materials
4 publications, 1.87%
|
|
Journal of Materials Chemistry C
|
Journal of Materials Chemistry C
3 publications, 1.4%
|
|
Journal of Luminescence
|
Journal of Luminescence
3 publications, 1.4%
|
|
Materials
|
Materials
3 publications, 1.4%
|
|
Angewandte Chemie - International Edition
|
Angewandte Chemie - International Edition
3 publications, 1.4%
|
|
Angewandte Chemie
|
Angewandte Chemie
3 publications, 1.4%
|
|
Small
|
Small
3 publications, 1.4%
|
|
ACS Energy Letters
|
ACS Energy Letters
3 publications, 1.4%
|
|
Energy and Environmental Science
|
Energy and Environmental Science
3 publications, 1.4%
|
|
Nature Energy
|
Nature Energy
2 publications, 0.93%
|
|
Energies
|
Energies
2 publications, 0.93%
|
|
Mendeleev Communications
|
Mendeleev Communications
2 publications, 0.93%
|
|
Chemical Engineering Journal
|
Chemical Engineering Journal
2 publications, 0.93%
|
|
Materials Today Chemistry
|
Materials Today Chemistry
2 publications, 0.93%
|
|
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
|
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
2 publications, 0.93%
|
|
Applied Physics Letters
|
Applied Physics Letters
2 publications, 0.93%
|
|
2
4
6
8
10
12
14
|
Citations by publishers
|
10
20
30
40
50
|
|
|
American Chemical Society (ACS)
|
American Chemical Society (ACS)
50 publications, 23.36%
|
|
Wiley
|
Wiley
49 publications, 22.9%
|
|
Elsevier
|
Elsevier
49 publications, 22.9%
|
|
Royal Society of Chemistry (RSC)
|
Royal Society of Chemistry (RSC)
21 publications, 9.81%
|
|
Multidisciplinary Digital Publishing Institute (MDPI)
|
Multidisciplinary Digital Publishing Institute (MDPI)
15 publications, 7.01%
|
|
Springer Nature
|
Springer Nature
9 publications, 4.21%
|
|
American Institute of Physics (AIP)
|
American Institute of Physics (AIP)
4 publications, 1.87%
|
|
Pleiades Publishing
|
Pleiades Publishing
2 publications, 0.93%
|
|
American Physical Society (APS)
|
American Physical Society (APS)
2 publications, 0.93%
|
|
IOP Publishing
|
IOP Publishing
2 publications, 0.93%
|
|
Cambridge University Press
|
Cambridge University Press
1 publication, 0.47%
|
|
Korean Ceramic Society
|
Korean Ceramic Society, 1, 0.47%
Korean Ceramic Society
1 publication, 0.47%
|
|
Optical Society of America
|
Optical Society of America
1 publication, 0.47%
|
|
American Association for the Advancement of Science (AAAS)
|
American Association for the Advancement of Science (AAAS)
1 publication, 0.47%
|
|
Chinese Physical Society
|
Chinese Physical Society
1 publication, 0.47%
|
|
Walter de Gruyter
|
Walter de Gruyter
1 publication, 0.47%
|
|
Hans Publishers
|
Hans Publishers
1 publication, 0.47%
|
|
10
20
30
40
50
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2017,2018,2019,2020,2021,2022,2023,2024],"ids":[0,0,0,0,0,0,0,0],"codes":[0,0,0,0,0,0,0,0],"imageUrls":["","","","","","","",""],"datasets":[{"label":"Citations number","data":[9,28,35,42,38,24,30,8],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["4.21","13.08","16.36","19.63","17.76","11.21","14.02","3.74"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Journal of Physical Chemistry Letters","ACS applied materials & interfaces","ACS Applied Energy Materials","Journal of Physical Chemistry C","Advanced Energy Materials","Solar RRL","Nano Energy","Journal of Materials Chemistry A","Advanced Functional Materials","Sustainable Energy and Fuels","Solar Energy","Solar Energy Materials and Solar Cells","Nanomaterials","Advanced Materials","Journal of Materials Chemistry C","Journal of Luminescence","Materials","Angewandte Chemie - International Edition","Angewandte Chemie","Small","ACS Energy Letters","Energy and Environmental Science","Nature Energy","Energies","Mendeleev Communications","Chemical Engineering Journal","Materials Today Chemistry","Russian Journal of Coordination Chemistry\/Koordinatsionnaya Khimiya","Applied Physics Letters"],"ids":[21963,1458,6419,8859,22475,25350,23236,14919,7715,14712,22255,5546,10051,25159,3848,7075,25198,19215,25450,9872,9022,10138,13790,23828,5294,16275,1350,12054,4202],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/ARM4e6URKRsbRZvIF0vFis9DjxGloBjnBYJXbHmZ_medium.webp"],"datasets":[{"label":"","data":[13,11,10,8,8,8,7,6,6,5,5,4,4,4,3,3,3,3,3,3,3,3,2,2,2,2,2,2,2],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[6.07,5.14,4.67,3.74,3.74,3.74,3.27,2.8,2.8,2.34,2.34,1.87,1.87,1.87,1.4,1.4,1.4,1.4,1.4,1.4,1.4,1.4,0.93,0.93,0.93,0.93,0.93,0.93,0.93],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["American Chemical Society (ACS)","Wiley","Elsevier","Royal Society of Chemistry (RSC)","Multidisciplinary Digital Publishing Institute (MDPI)","Springer Nature","American Institute of Physics (AIP)","Pleiades Publishing","American Physical Society (APS)","IOP Publishing","Cambridge University Press","Korean Ceramic Society","Optical Society of America","American Association for the Advancement of Science (AAAS)","Chinese Physical Society","Walter de Gruyter","Hans Publishers"],"ids":[40,11,17,123,202,8,250,101,1539,2075,1,1949,375,189,3809,4,8722],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/ARM4e6URKRsbRZvIF0vFis9DjxGloBjnBYJXbHmZ_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/nrK64iXHTzj43wMrfN1ZoUQ0vanswGzWPN45K3jA_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/cF81zWlLdkmYekymGuDcSdvgBGNKaIDoMoeJtHS1_medium.webp","","\/storage\/images\/resized\/bypZPcr6C4twKiQVCUCGc0GF4cH6aUWmpClD3hsH_medium.webp","\/storage\/images\/resized\/s10mcsCV4OAUg9O2KrqOquQC0PhyLMI8hUUkuflM_medium.webp","\/storage\/images\/resized\/uHl9M7oE4uFd6rEwxtu87cdHS4Etul2pdLbot8Qu_medium.webp","\/storage\/images\/resized\/3SpVxcYL33bOvPq4sHxJLH2NeKNeDloahSUpNiO4_medium.webp","\/storage\/images\/resized\/RJ5CyToQ8bANAfubYmoLtlA4KJKHWcRsvUmqs5XH_medium.webp"],"datasets":[{"label":"","data":[50,49,49,21,15,9,4,2,2,2,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[23.36,22.9,22.9,9.81,7.01,4.21,1.87,0.93,0.93,0.93,0.47,0.47,0.47,0.47,0.47,0.47,0.47],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Akbulatov A. F. et al. Probing the Intrinsic Thermal and Photochemical Stability of Hybrid and Inorganic Lead Halide Perovskites. // Journal of Physical Chemistry Letters. 2017. Vol. 8. No. 6. pp. 1211-1218.
GOST all authors (up to 50)
Copy
Akbulatov A. F., Luchkin S., Dremova N. N., Gerasimov K. L., ZHIDKOV I. S., Anokhin D. V., Kurmaev E. Z., Stevenson K. J., Troshin P. A. Probing the Intrinsic Thermal and Photochemical Stability of Hybrid and Inorganic Lead Halide Perovskites. // Journal of Physical Chemistry Letters. 2017. Vol. 8. No. 6. pp. 1211-1218.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.jpclett.6b03026
UR - https://doi.org/10.1021%2Facs.jpclett.6b03026
TI - Probing the Intrinsic Thermal and Photochemical Stability of Hybrid and Inorganic Lead Halide Perovskites.
T2 - Journal of Physical Chemistry Letters
AU - Dremova, Nadezhda N
AU - Gerasimov, Kirill L
AU - Anokhin, Denis V.
AU - ZHIDKOV, I. S.
AU - Stevenson, Keith J
AU - Troshin, Pavel A.
AU - Akbulatov, Azat F
AU - Luchkin, Sergey
AU - Kurmaev, E. Z.
PY - 2017
DA - 2017/03/02 00:00:00
PB - American Chemical Society (ACS)
SP - 1211-1218
IS - 6
VL - 8
SN - 1948-7185
ER -
Cite this
BibTex
Copy
@article{2017_Akbulatov,
author = {Nadezhda N Dremova and Kirill L Gerasimov and Denis V. Anokhin and I. S. ZHIDKOV and Keith J Stevenson and Pavel A. Troshin and Azat F Akbulatov and Sergey Luchkin and E. Z. Kurmaev},
title = {Probing the Intrinsic Thermal and Photochemical Stability of Hybrid and Inorganic Lead Halide Perovskites.},
journal = {Journal of Physical Chemistry Letters},
year = {2017},
volume = {8},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021%2Facs.jpclett.6b03026},
number = {6},
pages = {1211--1218},
doi = {10.1021/acs.jpclett.6b03026}
}
Cite this
MLA
Copy
Akbulatov, Azat F., et al. “Probing the Intrinsic Thermal and Photochemical Stability of Hybrid and Inorganic Lead Halide Perovskites..” Journal of Physical Chemistry Letters, vol. 8, no. 6, Mar. 2017, pp. 1211-1218. https://doi.org/10.1021%2Facs.jpclett.6b03026.