volume 24 issue 9 pages 2904-2911

Matrix-Free Thermally Activated Delayed Fluorescent Carbon Dots-Based Electroluminescent Light-Emitting Diodes Exceeding 5.6% External Quantum Efficiency

Publication typeJournal Article
Publication date2024-02-22
scimago Q1
wos Q1
SJR2.967
CiteScore14.9
Impact factor9.1
ISSN15306984, 15306992
General Chemistry
Condensed Matter Physics
General Materials Science
Mechanical Engineering
Bioengineering
Abstract
Carbon dots (CDs) are promising luminescent emission layer materials for next generation electroluminescent light emitting diodes (EL-LEDs) due to their many advantages, such as environmental friendliness, low cost, and high stability. However, limited by the spin-forbidden properties of the triplet transition, it is difficult to improve the external quantum efficiency (EQE) of fluorescent CDs-based EL-LEDs. Meanwhile, traditional thermally activated delayed fluorescent (TADF) CDs prepared using coating strategies are difficult to utilize in EL-LEDs due to the nonconductivity of the coating agent. Herein, we successfully developed matrix-free TADF CDs with yellow emission and achieved a device EQE of 5.68%, which is the highest value reported in CDs-based EL-LEDs. In addition, we also developed white EL-LEDs with an EQE of 1.70%. This study highlights the importance of interactions between precursors in modulating the electroluminescence properties of TADF emitters and provides an effective design principle for matrix-free TADF CDs.
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GOST Copy
Wang B. et al. Matrix-Free Thermally Activated Delayed Fluorescent Carbon Dots-Based Electroluminescent Light-Emitting Diodes Exceeding 5.6% External Quantum Efficiency // Nano Letters. 2024. Vol. 24. No. 9. pp. 2904-2911.
GOST all authors (up to 50) Copy
Wang B., Wang H., Wang H. W., Hu Y., Waterhouse G. I. N., Lu S. Matrix-Free Thermally Activated Delayed Fluorescent Carbon Dots-Based Electroluminescent Light-Emitting Diodes Exceeding 5.6% External Quantum Efficiency // Nano Letters. 2024. Vol. 24. No. 9. pp. 2904-2911.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acs.nanolett.4c00090
UR - https://pubs.acs.org/doi/10.1021/acs.nanolett.4c00090
TI - Matrix-Free Thermally Activated Delayed Fluorescent Carbon Dots-Based Electroluminescent Light-Emitting Diodes Exceeding 5.6% External Quantum Efficiency
T2 - Nano Letters
AU - Wang, Boyang
AU - Wang, Hongwei
AU - Wang, Hong Wei
AU - Hu, Yongsheng
AU - Waterhouse, Geoffrey I. N.
AU - Lu, Siyu
PY - 2024
DA - 2024/02/22
PB - American Chemical Society (ACS)
SP - 2904-2911
IS - 9
VL - 24
PMID - 38385631
SN - 1530-6984
SN - 1530-6992
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2024_Wang,
author = {Boyang Wang and Hongwei Wang and Hong Wei Wang and Yongsheng Hu and Geoffrey I. N. Waterhouse and Siyu Lu},
title = {Matrix-Free Thermally Activated Delayed Fluorescent Carbon Dots-Based Electroluminescent Light-Emitting Diodes Exceeding 5.6% External Quantum Efficiency},
journal = {Nano Letters},
year = {2024},
volume = {24},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://pubs.acs.org/doi/10.1021/acs.nanolett.4c00090},
number = {9},
pages = {2904--2911},
doi = {10.1021/acs.nanolett.4c00090}
}
MLA
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MLA Copy
Wang, Boyang, et al. “Matrix-Free Thermally Activated Delayed Fluorescent Carbon Dots-Based Electroluminescent Light-Emitting Diodes Exceeding 5.6% External Quantum Efficiency.” Nano Letters, vol. 24, no. 9, Feb. 2024, pp. 2904-2911. https://pubs.acs.org/doi/10.1021/acs.nanolett.4c00090.