Reactivity of LGe–NR2 and LGe(E)–NR2 over LGe–Cl and LGe(E)–Cl toward Me3SiX (L = Aminotroponiminate; NR2 = N(SiMe3)2/NC4H4; E = S/Se; X = Br/CN)
Publication type: Journal Article
Publication date: 2016-02-02
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The halogen exchange reaction of either germylene monochloride [LGeCl] (1) or germachalcogenoacid chlorides [LGe(E)Cl] (L = (i-Bu)2ATI; ATI = aminotroponiminate; E = S (V)/Se (VI)) with Me3SiX (X = Br/CN) did not occur. Therefore, the reactions of germanium compounds containing Ge–N bonds with Me3SiBr/CN were tried. Germylene amide [LGeN(SiMe3)2] (2) reacted with Me3SiBr to afford the aminotroponiminatogermylene monobromide [LGeBr] (3). Similarly, the chalcogen derivatives of compound 2, viz., germachalcogenoamides [LGe(E)N(SiMe3)2] (E = S 4 and Se 5) reacted with Me3SiBr and resulted in germachalcogenoacid bromides [LGe(E)Br] (E = S 6 and Se 7), respectively. N-Germylene pyrrole [LGeNC4H4] (2a) and N-germachalcogenoacylpyrroles [LGe(E)NC4H4] (E = S 4a, Se 5a) also reacted with Me3SiBr and afforded compounds 3, and 6−7 in excellent yields, respectively. Interestingly, the reaction of compound 2a with Me3SiCN afforded germanium(II) cyanide [LGeCN] (8). The difference in the reactivity of compounds (1, V, a...
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12
Total citations:
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Citations from 2024:
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(8.33%)
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Siwatch R. K. et al. Reactivity of LGe–NR2 and LGe(E)–NR2 over LGe–Cl and LGe(E)–Cl toward Me3SiX (L = Aminotroponiminate; NR2 = N(SiMe3)2/NC4H4; E = S/Se; X = Br/CN) // Organometallics. 2016. Vol. 35. No. 4. pp. 429-438.
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Siwatch R. K., Karwasara S., Sharma M. S., Mondal S., Mukherjee G., Rajaraman G., Nagendran S. Reactivity of LGe–NR2 and LGe(E)–NR2 over LGe–Cl and LGe(E)–Cl toward Me3SiX (L = Aminotroponiminate; NR2 = N(SiMe3)2/NC4H4; E = S/Se; X = Br/CN) // Organometallics. 2016. Vol. 35. No. 4. pp. 429-438.
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TY - JOUR
DO - 10.1021/acs.organomet.5b00643
UR - https://doi.org/10.1021/acs.organomet.5b00643
TI - Reactivity of LGe–NR2 and LGe(E)–NR2 over LGe–Cl and LGe(E)–Cl toward Me3SiX (L = Aminotroponiminate; NR2 = N(SiMe3)2/NC4H4; E = S/Se; X = Br/CN)
T2 - Organometallics
AU - Siwatch, Rahul Kumar
AU - Karwasara, Surendar
AU - Sharma, Manish Singh
AU - Mondal, Santigopal
AU - Mukherjee, Goutam
AU - Rajaraman, Gopalan
AU - Nagendran, Selvarajan
PY - 2016
DA - 2016/02/02
PB - American Chemical Society (ACS)
SP - 429-438
IS - 4
VL - 35
SN - 0276-7333
SN - 1520-6041
ER -
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BibTex (up to 50 authors)
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@article{2016_Siwatch,
author = {Rahul Kumar Siwatch and Surendar Karwasara and Manish Singh Sharma and Santigopal Mondal and Goutam Mukherjee and Gopalan Rajaraman and Selvarajan Nagendran},
title = {Reactivity of LGe–NR2 and LGe(E)–NR2 over LGe–Cl and LGe(E)–Cl toward Me3SiX (L = Aminotroponiminate; NR2 = N(SiMe3)2/NC4H4; E = S/Se; X = Br/CN)},
journal = {Organometallics},
year = {2016},
volume = {35},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/acs.organomet.5b00643},
number = {4},
pages = {429--438},
doi = {10.1021/acs.organomet.5b00643}
}
Cite this
MLA
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Siwatch, Rahul Kumar, et al. “Reactivity of LGe–NR2 and LGe(E)–NR2 over LGe–Cl and LGe(E)–Cl toward Me3SiX (L = Aminotroponiminate; NR2 = N(SiMe3)2/NC4H4; E = S/Se; X = Br/CN).” Organometallics, vol. 35, no. 4, Feb. 2016, pp. 429-438. https://doi.org/10.1021/acs.organomet.5b00643.