Hoveyda–Grubbs-Type Precatalysts with UnsymmetricalN-Heterocyclic Carbenes as Effective Catalysts in Olefin Metathesis
Publication type: Journal Article
Publication date: 2017-05-25
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
In our search for more-selective olefin metathesis catalysts, a series of Hoveyda–Grubbs-type second-generation complexes bearing unsymmetrical N-heterocyclic carbene (NHC) ligands were synthesized and tested in model reactions. It was found that the N-benzyl substituent in NHC has a positive influence on the selectivity of the newly obtained catalysts in the self-metathesis reaction of α-olefins. As expected, a typical relationship between activity and selectivity with respect to the N-aryl substituent used was observed. Dipp-containing complexes exhibited higher stability at elevated temperature, while Mes-bearing complexes typically gave better yields than their Dipp analogues.
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Total citations:
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Citations from 2024:
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GOST
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Małecki P. et al. Hoveyda–Grubbs-Type Precatalysts with UnsymmetricalN-Heterocyclic Carbenes as Effective Catalysts in Olefin Metathesis // Organometallics. 2017. Vol. 36. No. 11. pp. 2153-2166.
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Małecki P., Gajda K., Ablialimov O., Malinska M., Gajda R., Woźniak K., Kajetanowicz A., Grela K. Hoveyda–Grubbs-Type Precatalysts with UnsymmetricalN-Heterocyclic Carbenes as Effective Catalysts in Olefin Metathesis // Organometallics. 2017. Vol. 36. No. 11. pp. 2153-2166.
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RIS
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TY - JOUR
DO - 10.1021/acs.organomet.7b00211
UR - https://doi.org/10.1021/acs.organomet.7b00211
TI - Hoveyda–Grubbs-Type Precatalysts with UnsymmetricalN-Heterocyclic Carbenes as Effective Catalysts in Olefin Metathesis
T2 - Organometallics
AU - Małecki, Paweł
AU - Gajda, Katarzyna
AU - Ablialimov, Osman
AU - Malinska, Maura
AU - Gajda, Roman
AU - Woźniak, Krzysztof
AU - Kajetanowicz, Anna
AU - Grela, Karol
PY - 2017
DA - 2017/05/25
PB - American Chemical Society (ACS)
SP - 2153-2166
IS - 11
VL - 36
SN - 0276-7333
SN - 1520-6041
ER -
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BibTex (up to 50 authors)
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@article{2017_Małecki,
author = {Paweł Małecki and Katarzyna Gajda and Osman Ablialimov and Maura Malinska and Roman Gajda and Krzysztof Woźniak and Anna Kajetanowicz and Karol Grela},
title = {Hoveyda–Grubbs-Type Precatalysts with UnsymmetricalN-Heterocyclic Carbenes as Effective Catalysts in Olefin Metathesis},
journal = {Organometallics},
year = {2017},
volume = {36},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/acs.organomet.7b00211},
number = {11},
pages = {2153--2166},
doi = {10.1021/acs.organomet.7b00211}
}
Cite this
MLA
Copy
Małecki, Paweł, et al. “Hoveyda–Grubbs-Type Precatalysts with UnsymmetricalN-Heterocyclic Carbenes as Effective Catalysts in Olefin Metathesis.” Organometallics, vol. 36, no. 11, May. 2017, pp. 2153-2166. https://doi.org/10.1021/acs.organomet.7b00211.