Sustainable and Cost-Effective Suzuki–Miyaura Couplings toward the Key Biaryl Subunits of Arylex and Rinskor Active
2
Corteva Agriscience, 9330 Zionsville Road, Indianapolis, Indiana 46268, United States
|
Publication type: Journal Article
Publication date: 2020-06-10
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
32521158
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
Challenging Suzuki-Miyaura cross couplings associated with novel crop protection active ingredients from Corteva Agriscience, Arylex and Rinskor, can be performed in water using parts per million (ppm) levels of a Pd catalyst. Each coupling required a distinct set of reaction conditions to achieve maximum selectivities and chemical yields. By way of comparison, this chemistry is not only performed under environmentally responsible aqueous micellar conditions, but also involves lowering loadings (3-5 times) of endangered palladium than used previously to attain a more sustainable process.
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Metrics
31
Total citations:
31
Citations from 2025:
3
(9.68%)
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GOST
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Takale B. S. et al. Sustainable and Cost-Effective Suzuki–Miyaura Couplings toward the Key Biaryl Subunits of Arylex and Rinskor Active // Organic Letters. 2020. Vol. 22. No. 12. pp. 4823-4827.
GOST all authors (up to 50)
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Takale B. S., Irvine N. M., Schuitman A. D., Li X., Lipshutz B. H. Sustainable and Cost-Effective Suzuki–Miyaura Couplings toward the Key Biaryl Subunits of Arylex and Rinskor Active // Organic Letters. 2020. Vol. 22. No. 12. pp. 4823-4827.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.orglett.0c01625
UR - https://doi.org/10.1021/acs.orglett.0c01625
TI - Sustainable and Cost-Effective Suzuki–Miyaura Couplings toward the Key Biaryl Subunits of Arylex and Rinskor Active
T2 - Organic Letters
AU - Takale, Balaram S.
AU - Irvine, Nicholas M
AU - Schuitman, Abraham D
AU - Li, Xiaoyong
AU - Lipshutz, Bruce H.
PY - 2020
DA - 2020/06/10
PB - American Chemical Society (ACS)
SP - 4823-4827
IS - 12
VL - 22
PMID - 32521158
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2020_Takale,
author = {Balaram S. Takale and Nicholas M Irvine and Abraham D Schuitman and Xiaoyong Li and Bruce H. Lipshutz},
title = {Sustainable and Cost-Effective Suzuki–Miyaura Couplings toward the Key Biaryl Subunits of Arylex and Rinskor Active},
journal = {Organic Letters},
year = {2020},
volume = {22},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/acs.orglett.0c01625},
number = {12},
pages = {4823--4827},
doi = {10.1021/acs.orglett.0c01625}
}
Cite this
MLA
Copy
Takale, Balaram S., et al. “Sustainable and Cost-Effective Suzuki–Miyaura Couplings toward the Key Biaryl Subunits of Arylex and Rinskor Active.” Organic Letters, vol. 22, no. 12, Jun. 2020, pp. 4823-4827. https://doi.org/10.1021/acs.orglett.0c01625.