Protodesilylation of Arylsilanes by Visible-Light Photocatalysis
Publication type: Journal Article
Publication date: 2022-02-23
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
35196013
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
The first visible-light-mediated photocatalytic, metal- and base-free protodesilylation of arylsilanes is presented. The C(sp2)-Si bond cleavage process is catalyzed by a 5 mol % loading of a commercially available acridinium salt upon blue-light irradiation. Two simple approaches have been identified employing either aerobic or hydrogen atom transfer cocatalytic conditions, which enable the efficient and selective desilylation of a broad variety of simple and complex arylsilanes under mild conditions.
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9
Total citations:
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Citations from 2024:
7
(77%)
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GOST
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Kuhlmann J. H., Uygur M., García Mancheño O. Protodesilylation of Arylsilanes by Visible-Light Photocatalysis // Organic Letters. 2022. Vol. 24. No. 8. pp. 1689-1694.
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Kuhlmann J. H., Uygur M., García Mancheño O. Protodesilylation of Arylsilanes by Visible-Light Photocatalysis // Organic Letters. 2022. Vol. 24. No. 8. pp. 1689-1694.
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RIS
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TY - JOUR
DO - 10.1021/acs.orglett.2c00288
UR - https://doi.org/10.1021/acs.orglett.2c00288
TI - Protodesilylation of Arylsilanes by Visible-Light Photocatalysis
T2 - Organic Letters
AU - Kuhlmann, Jan H
AU - Uygur, Mustafa
AU - García Mancheño, Olga
PY - 2022
DA - 2022/02/23
PB - American Chemical Society (ACS)
SP - 1689-1694
IS - 8
VL - 24
PMID - 35196013
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
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@article{2022_Kuhlmann,
author = {Jan H Kuhlmann and Mustafa Uygur and Olga García Mancheño},
title = {Protodesilylation of Arylsilanes by Visible-Light Photocatalysis},
journal = {Organic Letters},
year = {2022},
volume = {24},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/acs.orglett.2c00288},
number = {8},
pages = {1689--1694},
doi = {10.1021/acs.orglett.2c00288}
}
Cite this
MLA
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Kuhlmann, Jan H., et al. “Protodesilylation of Arylsilanes by Visible-Light Photocatalysis.” Organic Letters, vol. 24, no. 8, Feb. 2022, pp. 1689-1694. https://doi.org/10.1021/acs.orglett.2c00288.