trans-Trifluoromethyltetrafluorosulfanyl Chloride: Selective Synthesis and Reaction with Diazo Compounds
Publication type: Journal Article
Publication date: 2022-11-04
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
36331806
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
trans-Trifluoromethyltetrafluorosulfanyl chloride (trans-CF3SF4Cl) is a unique reagent for the incorporation of the CF3SF4 group into organic compounds. However, CF3SF4Cl was prepared from hazardous reagents or formed as mixture of trans and cis isomers in low yield. Herein, a silver-promoted selective synthesis of trans-CF3SF4Cl under safe gas-reagent-free conditions is described. Furthermore, the synthetic application of trans-CF3SF4Cl is demonstrated through the new trifluoromethyltetrafluorosulfanylation of α-diazo carbonyl compounds.
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Metrics
11
Total citations:
11
Citations from 2024:
7
(63.63%)
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GOST
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Zhao X. et al. trans-Trifluoromethyltetrafluorosulfanyl Chloride: Selective Synthesis and Reaction with Diazo Compounds // Organic Letters. 2022. Vol. 24. No. 45. pp. 8412-8416.
GOST all authors (up to 50)
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Zhao X., Shou J. Y., Newton J. J., Qing F. trans-Trifluoromethyltetrafluorosulfanyl Chloride: Selective Synthesis and Reaction with Diazo Compounds // Organic Letters. 2022. Vol. 24. No. 45. pp. 8412-8416.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.orglett.2c03540
UR - https://doi.org/10.1021/acs.orglett.2c03540
TI - trans-Trifluoromethyltetrafluorosulfanyl Chloride: Selective Synthesis and Reaction with Diazo Compounds
T2 - Organic Letters
AU - Zhao, Xin
AU - Shou, Jia Yi
AU - Newton, Josiah J
AU - Qing, Fengling
PY - 2022
DA - 2022/11/04
PB - American Chemical Society (ACS)
SP - 8412-8416
IS - 45
VL - 24
PMID - 36331806
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
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@article{2022_Zhao,
author = {Xin Zhao and Jia Yi Shou and Josiah J Newton and Fengling Qing},
title = {trans-Trifluoromethyltetrafluorosulfanyl Chloride: Selective Synthesis and Reaction with Diazo Compounds},
journal = {Organic Letters},
year = {2022},
volume = {24},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/acs.orglett.2c03540},
number = {45},
pages = {8412--8416},
doi = {10.1021/acs.orglett.2c03540}
}
Cite this
MLA
Copy
Zhao, Xin, et al. “trans-Trifluoromethyltetrafluorosulfanyl Chloride: Selective Synthesis and Reaction with Diazo Compounds.” Organic Letters, vol. 24, no. 45, Nov. 2022, pp. 8412-8416. https://doi.org/10.1021/acs.orglett.2c03540.