Aza-ortho-Quinone Methide Promoted Strain-Release-Driven Conversion of Azabicyclo[1.1.0]butanes into Functionalized Azetidines
Тип публикации: Journal Article
Дата публикации: 2024-10-25
scimago Q1
wos Q1
white level БС1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5
ISSN: 15237060, 15237052
PubMed ID:
39453833
Краткое описание
A strategy for activating azabicyclo[1.1.0]butane (ABB) with in situ generated aza-ortho-quinone methide, promoted by HFIP, is reported. This unified activation, vis-à-vis strain-release-driven N/C3-functionalization, features a new means to prepare functionalized azetidines from ABB. Additionally, the newly installed motif on azetidine nitrogen could be forged into an indoline via Pd-catalyzed hydroamination, leveraging access to medicinally relevant scaffolds.
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Singh B. et al. Aza-ortho-Quinone Methide Promoted Strain-Release-Driven Conversion of Azabicyclo[1.1.0]butanes into Functionalized Azetidines // Organic Letters. 2024. Vol. 26. No. 44. pp. 9558-9563.
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Singh B., Sasmal P., Taites A., Hazra S., Saha J. Aza-ortho-Quinone Methide Promoted Strain-Release-Driven Conversion of Azabicyclo[1.1.0]butanes into Functionalized Azetidines // Organic Letters. 2024. Vol. 26. No. 44. pp. 9558-9563.
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TY - JOUR
DO - 10.1021/acs.orglett.4c03577
UR - https://pubs.acs.org/doi/10.1021/acs.orglett.4c03577
TI - Aza-ortho-Quinone Methide Promoted Strain-Release-Driven Conversion of Azabicyclo[1.1.0]butanes into Functionalized Azetidines
T2 - Organic Letters
AU - Singh, Bandana
AU - Sasmal, Pujan
AU - Taites, Aaron
AU - Hazra, Subhadeep
AU - Saha, Jaideep
PY - 2024
DA - 2024/10/25
PB - American Chemical Society (ACS)
SP - 9558-9563
IS - 44
VL - 26
PMID - 39453833
SN - 1523-7060
SN - 1523-7052
ER -
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@article{2024_Singh,
author = {Bandana Singh and Pujan Sasmal and Aaron Taites and Subhadeep Hazra and Jaideep Saha},
title = {Aza-ortho-Quinone Methide Promoted Strain-Release-Driven Conversion of Azabicyclo[1.1.0]butanes into Functionalized Azetidines},
journal = {Organic Letters},
year = {2024},
volume = {26},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://pubs.acs.org/doi/10.1021/acs.orglett.4c03577},
number = {44},
pages = {9558--9563},
doi = {10.1021/acs.orglett.4c03577}
}
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Singh, Bandana, et al. “Aza-ortho-Quinone Methide Promoted Strain-Release-Driven Conversion of Azabicyclo[1.1.0]butanes into Functionalized Azetidines.” Organic Letters, vol. 26, no. 44, Oct. 2024, pp. 9558-9563. https://pubs.acs.org/doi/10.1021/acs.orglett.4c03577.
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