High Trans Kinetic Selectivity in Ruthenium-Based Olefin Cross-Metathesis through Stereoretention
1
Materia, Inc., Pasadena, California 91107, United States
|
Publication type: Journal Article
Publication date: 2016-02-03
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
26840878
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
The first kinetically controlled, highly trans-selective (>98%) olefin cross-metathesis reaction is demonstrated using Ru-based catalysts. Reactions with either trans or cis olefins afford products with highly trans or cis stereochemistry, respectively. This E-selective olefin cross-metathesis is shown to occur between two trans olefins and between a trans olefin and a terminal olefin. Additionally, new stereoretentive catalysts have been synthesized for improved reactivity.
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73
Total citations:
73
Citations from 2024:
6
(8.22%)
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MLA
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GOST
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Johns A. et al. High Trans Kinetic Selectivity in Ruthenium-Based Olefin Cross-Metathesis through Stereoretention // Organic Letters. 2016. Vol. 18. No. 4. pp. 772-775.
GOST all authors (up to 50)
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Johns A., Ahmed T. S., Jackson B. W., Grubbs R. K., Pederson R. L. High Trans Kinetic Selectivity in Ruthenium-Based Olefin Cross-Metathesis through Stereoretention // Organic Letters. 2016. Vol. 18. No. 4. pp. 772-775.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.6b00031
UR - https://doi.org/10.1021/acs.orglett.6b00031
TI - High Trans Kinetic Selectivity in Ruthenium-Based Olefin Cross-Metathesis through Stereoretention
T2 - Organic Letters
AU - Johns, Adam
AU - Ahmed, Tonia S.
AU - Jackson, Bradford W
AU - Grubbs, Robert K.
AU - Pederson, Richard L.
PY - 2016
DA - 2016/02/03
PB - American Chemical Society (ACS)
SP - 772-775
IS - 4
VL - 18
PMID - 26840878
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2016_Johns,
author = {Adam Johns and Tonia S. Ahmed and Bradford W Jackson and Robert K. Grubbs and Richard L. Pederson},
title = {High Trans Kinetic Selectivity in Ruthenium-Based Olefin Cross-Metathesis through Stereoretention},
journal = {Organic Letters},
year = {2016},
volume = {18},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/acs.orglett.6b00031},
number = {4},
pages = {772--775},
doi = {10.1021/acs.orglett.6b00031}
}
Cite this
MLA
Copy
Johns, Adam, et al. “High Trans Kinetic Selectivity in Ruthenium-Based Olefin Cross-Metathesis through Stereoretention.” Organic Letters, vol. 18, no. 4, Feb. 2016, pp. 772-775. https://doi.org/10.1021/acs.orglett.6b00031.