Organic Letters

, том 18 , издание 21 , страницы 5476-5479

The Catalyst-Controlled Regiodivergent Chlorination of Phenols

Тип публикации: Journal Article

Дата публикации: 2016-10-18

American Chemical Society (ACS)

Organic Letters

scimago Q1

wos Q1

БС1

SJR: 1.235

CiteScore: 8.7

Impact factor: 5

ISSN: 15237060, 15237052

DOI: 10.1021/acs.orglett.6b02650

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PubMed ID: 27754679

Organic Chemistry

Biochemistry

Physical and Theoretical Chemistry

Краткое описание

Different catalysts are demonstrated to overcome or augment a substrate's innate regioselectivity. Nagasawa's bis-thiourea catalyst was found to overcome the innate para-selectivity of electrophilic phenol chlorination, yielding ortho-chlorinated phenols that are not readily obtainable via canonical electrophilic chlorinations. Conversely, a phosphine sulfide derived from 2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (BINAP) was found to enhance the innate para-preference of phenol chlorination.

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ГОСТ |

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ГОСТ Скопировать

Maddox S. M. et al. The Catalyst-Controlled Regiodivergent Chlorination of Phenols // Organic Letters. 2016. Vol. 18. No. 21. pp. 5476-5479.

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Maddox S. M., Dinh A., Armenta F., Um J., Gustafson J. L. The Catalyst-Controlled Regiodivergent Chlorination of Phenols // Organic Letters. 2016. Vol. 18. No. 21. pp. 5476-5479.

RIS |

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TY - JOUR

DO - 10.1021/acs.orglett.6b02650

UR - https://doi.org/10.1021/acs.orglett.6b02650

TI - The Catalyst-Controlled Regiodivergent Chlorination of Phenols

T2 - Organic Letters

AU - Maddox, Sean M

AU - Dinh, Andrew

AU - Armenta, Felipe

AU - Um, Joann

AU - Gustafson, Jeffrey L

PY - 2016

DA - 2016/10/18

PB - American Chemical Society (ACS)

SP - 5476-5479

IS - 21

VL - 18

PMID - 27754679

SN - 1523-7060

SN - 1523-7052

ER -

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@article{2016_Maddox,

author = {Sean M Maddox and Andrew Dinh and Felipe Armenta and Joann Um and Jeffrey L Gustafson},

title = {The Catalyst-Controlled Regiodivergent Chlorination of Phenols},

journal = {Organic Letters},

year = {2016},

volume = {18},

publisher = {American Chemical Society (ACS)},

month = {oct},

url = {https://doi.org/10.1021/acs.orglett.6b02650},

number = {21},

pages = {5476--5479},

doi = {10.1021/acs.orglett.6b02650}

}

MLA

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MLA Скопировать

Maddox, Sean M., et al. “The Catalyst-Controlled Regiodivergent Chlorination of Phenols.” Organic Letters, vol. 18, no. 21, Oct. 2016, pp. 5476-5479. https://doi.org/10.1021/acs.orglett.6b02650.

Издатель

American Chemical Society (ACS)

Журнал

Organic Letters

scimago Q1

wos Q1

БС1

SJR

1.235

CiteScore

8.7

Impact factor

ISSN

15237060 (Print)

15237052 (Electronic)