Asymmetric Hydrogenation of Dibenzo[c,e]azepine Derivatives with Chiral Cationic Ruthenium Diamine Catalysts
Publication type: Journal Article
Publication date: 2019-07-01
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
31259558
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
An efficient Ru-catalyzed asymmetric hydrogenation of dibenzo[c,e]azepines is reported. A series of seven-membered cyclic amines were obtained with moderate to excellent enantioselectivity. The catalyst counteranion played an important role in achieving high-level chiral induction. Moreover, a one-pot synthesis of chiral 6,7-dihydro-5H-dibenz[c,e]azepines via two-step reductive amination was also developed.
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36
Total citations:
36
Citations from 2025:
7
(19.44%)
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GOST
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Zhang S. et al. Asymmetric Hydrogenation of Dibenzo[c,e]azepine Derivatives with Chiral Cationic Ruthenium Diamine Catalysts // Organic Letters. 2019. Vol. 21. No. 14. pp. 5538-5541.
GOST all authors (up to 50)
Copy
Zhang S., Chen F., He Y., Fan Q. Asymmetric Hydrogenation of Dibenzo[c,e]azepine Derivatives with Chiral Cationic Ruthenium Diamine Catalysts // Organic Letters. 2019. Vol. 21. No. 14. pp. 5538-5541.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.9b01859
UR - https://doi.org/10.1021/acs.orglett.9b01859
TI - Asymmetric Hydrogenation of Dibenzo[c,e]azepine Derivatives with Chiral Cationic Ruthenium Diamine Catalysts
T2 - Organic Letters
AU - Zhang, Shanshan
AU - Chen, Fei
AU - He, Yan-Mei
AU - Fan, Qing-Hua
PY - 2019
DA - 2019/07/01
PB - American Chemical Society (ACS)
SP - 5538-5541
IS - 14
VL - 21
PMID - 31259558
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2019_Zhang,
author = {Shanshan Zhang and Fei Chen and Yan-Mei He and Qing-Hua Fan},
title = {Asymmetric Hydrogenation of Dibenzo[c,e]azepine Derivatives with Chiral Cationic Ruthenium Diamine Catalysts},
journal = {Organic Letters},
year = {2019},
volume = {21},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/acs.orglett.9b01859},
number = {14},
pages = {5538--5541},
doi = {10.1021/acs.orglett.9b01859}
}
Cite this
MLA
Copy
Zhang, Shanshan, et al. “Asymmetric Hydrogenation of Dibenzo[c,e]azepine Derivatives with Chiral Cationic Ruthenium Diamine Catalysts.” Organic Letters, vol. 21, no. 14, Jul. 2019, pp. 5538-5541. https://doi.org/10.1021/acs.orglett.9b01859.