Cyclic Alkyl Amino Ruthenium Complexes—Efficient Catalysts for Macrocyclization and Acrylonitrile Cross Metathesis
Rafał Gawin
1
,
Andrzej Tracz
1
,
Michał Chwalba
1
,
Anna Kozakiewicz
2
,
Bartosz Trzaskowski
3
,
Krzysztof Skowerski
1
1
Apeiron Synthesis SA ul., Duńska 9, 54-427 Wrocław, Poland
|
2
Faculty of Chemistry, University of Nicolaus Copernicus, Gagarina 7, 87-100 Toruń, Poland
|
Тип публикации: Journal Article
Дата публикации: 2017-07-20
scimago Q1
wos Q1
БС1
SJR: 3.782
CiteScore: 19.5
Impact factor: 13.1
ISSN: 21555435
General Chemistry
Catalysis
Краткое описание
The active species generated from ruthenium complexes bearing N-heterocyclic carbene (NHC) ligands exhibit limited stability under certain conditions (high dilution, high temperature) and in the presence of nitrile functionality. As a consequence, industrial implementation of metathesis for the production of important materials such as macrocyclic musks and polyamide 11 is uneconomical. Over the past decade, hundreds of ruthenium complexes bearing NHC ligands have been obtained. However, to this date, they have brought rather limited improvements in efficiency. In this paper, we report on cyclic alkyl amino carbene (CAAC) ruthenium complexes that promote highly challenging macrocyclization and cross metathesis (CM) with acrylonitrile reactions at loadings as low as 10–20 ppm.
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Gawin R. et al. Cyclic Alkyl Amino Ruthenium Complexes—Efficient Catalysts for Macrocyclization and Acrylonitrile Cross Metathesis // ACS Catalysis. 2017. Vol. 7. No. 8. pp. 5443-5449.
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Gawin R., Tracz A., Chwalba M., Kozakiewicz A., Trzaskowski B., Skowerski K. Cyclic Alkyl Amino Ruthenium Complexes—Efficient Catalysts for Macrocyclization and Acrylonitrile Cross Metathesis // ACS Catalysis. 2017. Vol. 7. No. 8. pp. 5443-5449.
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TY - JOUR
DO - 10.1021/acscatal.7b00597
UR - https://doi.org/10.1021/acscatal.7b00597
TI - Cyclic Alkyl Amino Ruthenium Complexes—Efficient Catalysts for Macrocyclization and Acrylonitrile Cross Metathesis
T2 - ACS Catalysis
AU - Gawin, Rafał
AU - Tracz, Andrzej
AU - Chwalba, Michał
AU - Kozakiewicz, Anna
AU - Trzaskowski, Bartosz
AU - Skowerski, Krzysztof
PY - 2017
DA - 2017/07/20
PB - American Chemical Society (ACS)
SP - 5443-5449
IS - 8
VL - 7
SN - 2155-5435
ER -
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@article{2017_Gawin,
author = {Rafał Gawin and Andrzej Tracz and Michał Chwalba and Anna Kozakiewicz and Bartosz Trzaskowski and Krzysztof Skowerski},
title = {Cyclic Alkyl Amino Ruthenium Complexes—Efficient Catalysts for Macrocyclization and Acrylonitrile Cross Metathesis},
journal = {ACS Catalysis},
year = {2017},
volume = {7},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/acscatal.7b00597},
number = {8},
pages = {5443--5449},
doi = {10.1021/acscatal.7b00597}
}
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MLA
Скопировать
Gawin, Rafał, et al. “Cyclic Alkyl Amino Ruthenium Complexes—Efficient Catalysts for Macrocyclization and Acrylonitrile Cross Metathesis.” ACS Catalysis, vol. 7, no. 8, Jul. 2017, pp. 5443-5449. https://doi.org/10.1021/acscatal.7b00597.