The Photochemistry of Amino Acids Produced on the Polar Cryovolcanic Regions of Titan
Diogo Gonçalves
1, 2
,
Florence Hofmann
3
,
Severin Wipf
3
,
Riccardo Giovanni Urso
4
,
Jana Bocková
5, 6
,
J Bocková
6
,
Cornelia Meinert
5, 6
,
Paul B. Rimmer
7
,
Gautam D Stroscio
8, 9
,
Nir Goldman
8, 9, 10, 11, 12, 13
,
Andreas Elsaesser
3
,
Bruno Pedras
2, 14
,
4
10
Department of Chemical Engineering
11
University Of California
|
12
Department of Chemical Engineering, Davis, United States
|
Publication type: Journal Article
Publication date: 2025-03-08
scimago Q2
wos Q2
SJR: 0.844
CiteScore: 5.9
Impact factor: 2.9
ISSN: 24723452
Abstract
The cryovolcanic regions of Titan offer transient opportunities for prebiotic molecules to exist in water–ammonia solutions on the surface of the Saturnian moon. The upcoming NASA's Dragonfly mission will search for high nitrogen concentrations and amino acids on Titan's equatorial terrains. Cryovolcanic features, however, are most common on the polar regions. To mitigate the distance, bubble bursting may encapsulate the prebiotic molecules into aerosols, which Titan's Hadley circulation would subsequently transport to the equator. We investigate whether alanine and glycine survive this meridional journey. Despite the unconstrained meridional wind velocities, our results suggest that the amino acids can survive the transport through the mesosphere. Dragonfly may find cryo-volcanogenic amino acids on Titan's equator. Further, the interaction between the two amino acids increased 10-fold the photodegradation rate of glycine. We justify it based on changes in the environment polarity.
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Gonçalves D. et al. The Photochemistry of Amino Acids Produced on the Polar Cryovolcanic Regions of Titan // ACS Earth and Space Chemistry. 2025. Vol. 9. No. 3. pp. 715-728.
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Gonçalves D., Hofmann F., Wipf S., Urso R. G., Bocková J., Bocková J., Meinert C., Rimmer P. B., Stroscio G. D., Goldman N., Elsaesser A., Pedras B., Martins Z. The Photochemistry of Amino Acids Produced on the Polar Cryovolcanic Regions of Titan // ACS Earth and Space Chemistry. 2025. Vol. 9. No. 3. pp. 715-728.
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TY - JOUR
DO - 10.1021/acsearthspacechem.4c00376
UR - https://pubs.acs.org/doi/10.1021/acsearthspacechem.4c00376
TI - The Photochemistry of Amino Acids Produced on the Polar Cryovolcanic Regions of Titan
T2 - ACS Earth and Space Chemistry
AU - Gonçalves, Diogo
AU - Hofmann, Florence
AU - Wipf, Severin
AU - Urso, Riccardo Giovanni
AU - Bocková, Jana
AU - Bocková, J
AU - Meinert, Cornelia
AU - Rimmer, Paul B.
AU - Stroscio, Gautam D
AU - Goldman, Nir
AU - Elsaesser, Andreas
AU - Pedras, Bruno
AU - Martins, Zita
PY - 2025
DA - 2025/03/08
PB - American Chemical Society (ACS)
SP - 715-728
IS - 3
VL - 9
SN - 2472-3452
ER -
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@article{2025_Gonçalves,
author = {Diogo Gonçalves and Florence Hofmann and Severin Wipf and Riccardo Giovanni Urso and Jana Bocková and J Bocková and Cornelia Meinert and Paul B. Rimmer and Gautam D Stroscio and Nir Goldman and Andreas Elsaesser and Bruno Pedras and Zita Martins},
title = {The Photochemistry of Amino Acids Produced on the Polar Cryovolcanic Regions of Titan},
journal = {ACS Earth and Space Chemistry},
year = {2025},
volume = {9},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://pubs.acs.org/doi/10.1021/acsearthspacechem.4c00376},
number = {3},
pages = {715--728},
doi = {10.1021/acsearthspacechem.4c00376}
}
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Gonçalves, Diogo, et al. “The Photochemistry of Amino Acids Produced on the Polar Cryovolcanic Regions of Titan.” ACS Earth and Space Chemistry, vol. 9, no. 3, Mar. 2025, pp. 715-728. https://pubs.acs.org/doi/10.1021/acsearthspacechem.4c00376.