Inorganic Chemistry, volume 50, issue 10, pages 4307-4312
“Jumping Crystals”: Oxygen-Evolving Metal-Nitroxide Complexes
Ovcharenko V.
1
,
Fokin Sergei V
1
,
Fursova Elena Yu.
1
,
Kuznetsova O.V.
1
,
Tretyakov Eugene V
1
,
Romanenko G.
1
,
Publication type: Journal Article
Publication date: 2011-04-14
Journal:
Inorganic Chemistry
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.6
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The crystals of heterospin complexes [M(hfac)(2)L(2)] (where M = Cu, Ni, Co, or Mn; hfac = hexafluoroacetylacetonate; and L = nitronyl nitroxide, 4,4,5,5-tetramethyl-2-(1-methyl-1H-imidazol-5-yl)-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl) were found to make unusual jumping motions. Under ambient conditions, the jumping and various displacements of crystals lasted for several weeks. The mechanical motion was accompanied by the cracking and disintegration of crystals, and a solid [M(hfac)(2)(L(1))(2)] complex with the corresponding imino nitroxide 4,4,5,5-tetramethyl-2-(1-methyl-1H-imidazol-5-yl)-4,5-dihydro-1H-imidazole-1-oxyl (L(1)) was detected. The jumping was accompanied by the spontaneous elimination of oxygen, the source of which was the nitronyl nitroxyl fragment of coordinated L. An X-ray study of [M(hfac)(2)L(2)] (where M = Cu, Ni, Co, or Mn) showed that the molecular structure of all [M(hfac)(2)L(2)] and their packing in the solid state were identical. The packing of [M(hfac)(2)L(2)] was concluded to be critical to the mechanical effect. In complexes with different stoichiometries or different sets of diamagnetic ligands ([Cu(hfac)(2)L](2), [Cu(hfac)(acac)L]·EtOH, [CuPiv(2)L(2)]·2CH(2)Cl(2), and [Cu(hfac)(2)L(2)Cu(2)Piv(4)]·3C(7)H(8) (where acac is acetylacetonate and Piv is trimethylacetate), or free L), the effect vanished when the packing changed.
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Citations by publishers
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Ovcharenko V. et al. “Jumping Crystals”: Oxygen-Evolving Metal-Nitroxide Complexes // Inorganic Chemistry. 2011. Vol. 50. No. 10. pp. 4307-4312.
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Ovcharenko V., Fokin S. V., Fursova E. Y., Kuznetsova O., Tretyakov E. V., Romanenko G., Bogomyakov A. S. “Jumping Crystals”: Oxygen-Evolving Metal-Nitroxide Complexes // Inorganic Chemistry. 2011. Vol. 50. No. 10. pp. 4307-4312.
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TY - JOUR
DO - 10.1021/ic1022483
UR - https://doi.org/10.1021%2Fic1022483
TI - “Jumping Crystals”: Oxygen-Evolving Metal-Nitroxide Complexes
T2 - Inorganic Chemistry
AU - Fokin, Sergei V
AU - Fursova, Elena Yu.
AU - Tretyakov, Eugene V
AU - Ovcharenko, V.
AU - Kuznetsova, O.V.
AU - Romanenko, G.
AU - Bogomyakov, Artem S
PY - 2011
DA - 2011/04/14 00:00:00
PB - American Chemical Society (ACS)
SP - 4307-4312
IS - 10
VL - 50
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2011_Ovcharenko,
author = {Sergei V Fokin and Elena Yu. Fursova and Eugene V Tretyakov and V. Ovcharenko and O.V. Kuznetsova and G. Romanenko and Artem S Bogomyakov},
title = {“Jumping Crystals”: Oxygen-Evolving Metal-Nitroxide Complexes},
journal = {Inorganic Chemistry},
year = {2011},
volume = {50},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021%2Fic1022483},
number = {10},
pages = {4307--4312},
doi = {10.1021/ic1022483}
}
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Ovcharenko, V., et al. ““Jumping Crystals”: Oxygen-Evolving Metal-Nitroxide Complexes.” Inorganic Chemistry, vol. 50, no. 10, Apr. 2011, pp. 4307-4312. https://doi.org/10.1021%2Fic1022483.