Copper(I) Thiocyanate-Amine Networks: Synthesis, Structure, and Luminescence Behavior.
Publication type: Journal Article
Publication date: 2011-08-01
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
21728324
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
A series of metal-organic networks of CuSCN were prepared by direct reactions with substituted pyridine and aliphatic amine ligands, L. Thiocyanate bridging is seen in all but 1 of 11 new X-ray structures. Structures are reported for (CuSCN)L sheets (L = 3-chloro- and 3-bromopyridine, N-methylmorpholine), ladders (L = 2-ethylpyridine, N-methylpiperidine), and chains (L = 2,4,6-collidine). X-ray structures of (CuSCN)L(2) are chains (L = 4-ethyl- and 4-t-butylpyridine, piperidine, and morpholine). A unique N-thiocyanato monomer structure, (CuSCN)(3-ethylpyridine)(3), is also reported. In most cases, amine ligands are thermally released at temperatures <100 °C. Strong yellow-to-green luminescence at ambient temperature is observed for the substituted pyridine complexes. High solid state quantum efficiencies are seen for many of the CuSCN-L complexes. Microsecond phosphorescence lifetimes seen for CuSCN-L are in direct contrast to the nanosecond-lifetime emission of CuSCN. MLCT associated with pyridine π* orbitals is proposed as the excitation mechanism.
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59
Total citations:
59
Citations from 2024:
6
(10.16%)
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Miller K. M. et al. Copper(I) Thiocyanate-Amine Networks: Synthesis, Structure, and Luminescence Behavior. // Inorganic Chemistry. 2011. Vol. 50. No. 15. pp. 7239-7249.
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Miller K. M. Copper(I) Thiocyanate-Amine Networks: Synthesis, Structure, and Luminescence Behavior. // Inorganic Chemistry. 2011. Vol. 50. No. 15. pp. 7239-7249.
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TY - JOUR
DO - 10.1021/ic200821f
UR - https://doi.org/10.1021/ic200821f
TI - Copper(I) Thiocyanate-Amine Networks: Synthesis, Structure, and Luminescence Behavior.
T2 - Inorganic Chemistry
AU - Miller, Kayla M.
PY - 2011
DA - 2011/08/01
PB - American Chemical Society (ACS)
SP - 7239-7249
IS - 15
VL - 50
PMID - 21728324
SN - 0020-1669
SN - 1520-510X
ER -
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BibTex (up to 50 authors)
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@article{2011_Miller,
author = {Kayla M. Miller},
title = {Copper(I) Thiocyanate-Amine Networks: Synthesis, Structure, and Luminescence Behavior.},
journal = {Inorganic Chemistry},
year = {2011},
volume = {50},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/ic200821f},
number = {15},
pages = {7239--7249},
doi = {10.1021/ic200821f}
}
Cite this
MLA
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Miller, Kayla M., et al. “Copper(I) Thiocyanate-Amine Networks: Synthesis, Structure, and Luminescence Behavior..” Inorganic Chemistry, vol. 50, no. 15, Aug. 2011, pp. 7239-7249. https://doi.org/10.1021/ic200821f.