Photoequilibration of 2-naphthylcarbene and 2,3-benzobicyclo[4.1.0]hepta-2,4,6-triene
Publication type: Journal Article
Publication date: 1993-02-01
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
Irradiation (λ>300 nm or λ=480±6 nm) of 2-naphthyldiazomethane (4), matrix-isolated in argon at 10 K, gives a mixture of 2-naphthylcarbene (1) and 2,3-benzobicyclo[4.1.0]hepta-2,4,6-triene (2). 2-Naphthylcarbene (1) is characterized by infrared, UV/visible, and ESR spectroscopy and by chemical trapping with CO. 2,3-Benzobicyclo[4.1.0]hepta-2,4,6-triene (2) is characterized by infrared and UV/visible spectroscopy. A photoequilibrium exists between carbene 1 and bicyclic compound 2. Photolysis (λ=290±6 nm) of bicyclic compound 2 results exclusively in ring-opening to carbene 1
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Total citations:
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Albrecht S. W., McMahon R. J. Photoequilibration of 2-naphthylcarbene and 2,3-benzobicyclo[4.1.0]hepta-2,4,6-triene // Journal of the American Chemical Society. 1993. Vol. 115. No. 3. pp. 855-859.
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Albrecht S. W., McMahon R. J. Photoequilibration of 2-naphthylcarbene and 2,3-benzobicyclo[4.1.0]hepta-2,4,6-triene // Journal of the American Chemical Society. 1993. Vol. 115. No. 3. pp. 855-859.
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RIS
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TY - JOUR
DO - 10.1021/ja00056a005
UR - https://doi.org/10.1021/ja00056a005
TI - Photoequilibration of 2-naphthylcarbene and 2,3-benzobicyclo[4.1.0]hepta-2,4,6-triene
T2 - Journal of the American Chemical Society
AU - Albrecht, Steven W
AU - McMahon, R. J.
PY - 1993
DA - 1993/02/01
PB - American Chemical Society (ACS)
SP - 855-859
IS - 3
VL - 115
SN - 0002-7863
SN - 1520-5126
ER -
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BibTex (up to 50 authors)
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@article{1993_Albrecht,
author = {Steven W Albrecht and R. J. McMahon},
title = {Photoequilibration of 2-naphthylcarbene and 2,3-benzobicyclo[4.1.0]hepta-2,4,6-triene},
journal = {Journal of the American Chemical Society},
year = {1993},
volume = {115},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/ja00056a005},
number = {3},
pages = {855--859},
doi = {10.1021/ja00056a005}
}
Cite this
MLA
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Albrecht, Steven W., and R. J. McMahon. “Photoequilibration of 2-naphthylcarbene and 2,3-benzobicyclo[4.1.0]hepta-2,4,6-triene.” Journal of the American Chemical Society, vol. 115, no. 3, Feb. 1993, pp. 855-859. https://doi.org/10.1021/ja00056a005.