Biomimetic Asymmetric Hydrogenation: In Situ Regenerable Hantzsch Esters for Asymmetric Hydrogenation of Benzoxazinones
Publication type: Journal Article
Publication date: 2011-09-23
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
21932832
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
A catalytic amount of Hantzsch ester that could be regenerated in situ by Ru complexes under hydrogen gas has been employed in the biomimetic asymmetric hydrogenation of benzoxazinones with up to 99% ee in the presence of chiral phosphoric acid. The use of hydrogen gas as a reductant for the regeneration of Hantzsch esters makes this hydrogenation an ideal atom economic process.
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Metrics
191
Total citations:
191
Citations from 2024:
15
(7.85%)
Cite this
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BibTex |
MLA
Cite this
GOST
Copy
Chen Q. et al. Biomimetic Asymmetric Hydrogenation: In Situ Regenerable Hantzsch Esters for Asymmetric Hydrogenation of Benzoxazinones // Journal of the American Chemical Society. 2011. Vol. 133. No. 41. pp. 16432-16435.
GOST all authors (up to 50)
Copy
Chen Q., Chen M., Yu C. B., Shi L., Wang D. S., Yang Y., Zhou Y. Biomimetic Asymmetric Hydrogenation: In Situ Regenerable Hantzsch Esters for Asymmetric Hydrogenation of Benzoxazinones // Journal of the American Chemical Society. 2011. Vol. 133. No. 41. pp. 16432-16435.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ja208073w
UR - https://doi.org/10.1021/ja208073w
TI - Biomimetic Asymmetric Hydrogenation: In Situ Regenerable Hantzsch Esters for Asymmetric Hydrogenation of Benzoxazinones
T2 - Journal of the American Chemical Society
AU - Chen, Qingan
AU - Chen, Muwang
AU - Yu, Chang Bin
AU - Shi, Lei
AU - Wang, Duo Sheng
AU - Yang, Yan
AU - Zhou, Yonggui
PY - 2011
DA - 2011/09/23
PB - American Chemical Society (ACS)
SP - 16432-16435
IS - 41
VL - 133
PMID - 21932832
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2011_Chen,
author = {Qingan Chen and Muwang Chen and Chang Bin Yu and Lei Shi and Duo Sheng Wang and Yan Yang and Yonggui Zhou},
title = {Biomimetic Asymmetric Hydrogenation: In Situ Regenerable Hantzsch Esters for Asymmetric Hydrogenation of Benzoxazinones},
journal = {Journal of the American Chemical Society},
year = {2011},
volume = {133},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/ja208073w},
number = {41},
pages = {16432--16435},
doi = {10.1021/ja208073w}
}
Cite this
MLA
Copy
Chen, Qingan, et al. “Biomimetic Asymmetric Hydrogenation: In Situ Regenerable Hantzsch Esters for Asymmetric Hydrogenation of Benzoxazinones.” Journal of the American Chemical Society, vol. 133, no. 41, Sep. 2011, pp. 16432-16435. https://doi.org/10.1021/ja208073w.