Volatile Single-Source Molecular Precursor for the Lithium Ion Battery Cathode
Publication type: Journal Article
Publication date: 2012-03-23
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
22443098
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
The first single-source molecular precursor for a lithium-manganese cathode material is reported. Heterometallic β-diketonate LiMn(2)(thd)(5) (1, thd = 2,2,6,6-tetramethyl-3,5-heptanedionate) was obtained in high yield by simple one-step solid-state reactions employing commercially available reagents. Substantial scale-up preparation of 1 was achieved using a solution approach. The crystal structure of the precursor contains discrete Li:Mn = 1:2 trinuclear molecules held together by bridging diketonate ligands. The complex is relatively stable in open air, highly volatile, and soluble in all common solvents. It was confirmed to retain its heterometallic structure in solutions of non-coordinating solvents. The heterometallic diketonate 1 was shown to exhibit clean, low-temperature decomposition in air/oxygen that results in nanosized particles of spinel-type oxide LiMn(2)O(4), one of the leading cathode materials for lithium ion batteries.
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44
Total citations:
44
Citations from 2024:
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(13.64%)
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GOST
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Navulla A. et al. Volatile Single-Source Molecular Precursor for the Lithium Ion Battery Cathode // Journal of the American Chemical Society. 2012. Vol. 134. No. 13. pp. 5762-5765.
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Navulla A., Huynh L., Wei Z., Filatov A. Y., Dikarev E. V. Volatile Single-Source Molecular Precursor for the Lithium Ion Battery Cathode // Journal of the American Chemical Society. 2012. Vol. 134. No. 13. pp. 5762-5765.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ja301112q
UR - https://doi.org/10.1021/ja301112q
TI - Volatile Single-Source Molecular Precursor for the Lithium Ion Battery Cathode
T2 - Journal of the American Chemical Society
AU - Navulla, Anantharamulu
AU - Huynh, Lan
AU - Wei, Zheng
AU - Filatov, Alexander Yu.
AU - Dikarev, Evgeny V.
PY - 2012
DA - 2012/03/23
PB - American Chemical Society (ACS)
SP - 5762-5765
IS - 13
VL - 134
PMID - 22443098
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2012_Navulla,
author = {Anantharamulu Navulla and Lan Huynh and Zheng Wei and Alexander Yu. Filatov and Evgeny V. Dikarev},
title = {Volatile Single-Source Molecular Precursor for the Lithium Ion Battery Cathode},
journal = {Journal of the American Chemical Society},
year = {2012},
volume = {134},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/ja301112q},
number = {13},
pages = {5762--5765},
doi = {10.1021/ja301112q}
}
Cite this
MLA
Copy
Navulla, Anantharamulu, et al. “Volatile Single-Source Molecular Precursor for the Lithium Ion Battery Cathode.” Journal of the American Chemical Society, vol. 134, no. 13, Mar. 2012, pp. 5762-5765. https://doi.org/10.1021/ja301112q.