Journal of the American Chemical Society, volume 131, issue 4, pages 1410-1412
Synthesis and Structure Revision of Nakiterpiosin
Publication type: Journal Article
Publication date: 2008-11-08
scimago Q1
SJR: 5.489
CiteScore: 24.4
Impact factor: 14.4
ISSN: 00027863, 15205126
PubMed ID:
18998640
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
This manuscript describes a convergent synthesis and the revision of the relative stereochemistry of nakiterpiosin, a marine C-nor-D-homosteroid. Our synthesis features a late-stage carbonylative Stille cross-coupling reaction and a photo-Nazarov cyclization reaction that deliver the complete nakiterpiosin skeleton efficiently.
Found
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