Journal of the American Chemical Society, volume 131, issue 4, pages 1410-1412

Synthesis and Structure Revision of Nakiterpiosin

Publication typeJournal Article
Publication date2008-11-08
scimago Q1
SJR5.489
CiteScore24.4
Impact factor14.4
ISSN00027863, 15205126
PubMed ID:  18998640
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
This manuscript describes a convergent synthesis and the revision of the relative stereochemistry of nakiterpiosin, a marine C-nor-D-homosteroid. Our synthesis features a late-stage carbonylative Stille cross-coupling reaction and a photo-Nazarov cyclization reaction that deliver the complete nakiterpiosin skeleton efficiently.
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