Journal of the American Chemical Society, volume 142, issue 15, pages 7218-7224

Record Complexity in the Polycatenation of Three Porous Hydrogen-Bonded Organic Frameworks with Stepwise Adsorption Behaviors

Li Yu-Lin 1
Yin Qi 1
Li Lan 1, 4
Fang Zhi-Bin 1
Publication typeJournal Article
Publication date2020-03-26
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor15
ISSN00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
Hydrogen-bonded organic frameworks (HOFs) show great potential in many applications, but few structure-property correlations have been explored in this field. In this work, we report that self-assembly of a rigid and planar ligand gives rise to flat hexagonal honeycomb motifs which are extended into undulated two-dimensional (2D) layers and finally generate three polycatenated HOFs with record complexity. This kind of undulation is absent in the 2D layers built from a very similar but nonplanar ligand, indicating that a slight torsion of ligand produces overwhelming structural change. This change delivers materials with unique stepwise adsorption behaviors under a certain pressure originating from the movement between mutually interwoven hexagonal networks. Meanwhile, high chemical stability, phase transformation, and preferential adsorption of aromatic compounds were observed in these HOFs. The results presented in this work would help us to understand the self-assembly behaviors of HOFs and shed light on the rational design of HOF materials for practical applications.

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Li Y. et al. Record Complexity in the Polycatenation of Three Porous Hydrogen-Bonded Organic Frameworks with Stepwise Adsorption Behaviors // Journal of the American Chemical Society. 2020. Vol. 142. No. 15. pp. 7218-7224.
GOST all authors (up to 50) Copy
Li Y., Alexandrov E. V., Yin Q., Li L., Fang Z., Yuan W., Proserpio D. M., Liu T. Record Complexity in the Polycatenation of Three Porous Hydrogen-Bonded Organic Frameworks with Stepwise Adsorption Behaviors // Journal of the American Chemical Society. 2020. Vol. 142. No. 15. pp. 7218-7224.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/jacs.0c02406
UR - https://doi.org/10.1021%2Fjacs.0c02406
TI - Record Complexity in the Polycatenation of Three Porous Hydrogen-Bonded Organic Frameworks with Stepwise Adsorption Behaviors
T2 - Journal of the American Chemical Society
AU - Li, Yu-Lin
AU - Alexandrov, Eugeny V.
AU - Li, Lan
AU - Yuan, Wen-Bing
AU - Proserpio, Davide M.
AU - Liu, Tian-Fu
AU - Yin, Qi
AU - Fang, Zhi-Bin
PY - 2020
DA - 2020/03/26 00:00:00
PB - American Chemical Society (ACS)
SP - 7218-7224
IS - 15
VL - 142
SN - 0002-7863
SN - 1520-5126
ER -
BibTex |
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BibTex Copy
@article{2020_Li,
author = {Yu-Lin Li and Eugeny V. Alexandrov and Lan Li and Wen-Bing Yuan and Davide M. Proserpio and Tian-Fu Liu and Qi Yin and Zhi-Bin Fang},
title = {Record Complexity in the Polycatenation of Three Porous Hydrogen-Bonded Organic Frameworks with Stepwise Adsorption Behaviors},
journal = {Journal of the American Chemical Society},
year = {2020},
volume = {142},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021%2Fjacs.0c02406},
number = {15},
pages = {7218--7224},
doi = {10.1021/jacs.0c02406}
}
MLA
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MLA Copy
Li, Yu-Lin, et al. ā€œRecord Complexity in the Polycatenation of Three Porous Hydrogen-Bonded Organic Frameworks with Stepwise Adsorption Behaviors.ā€ Journal of the American Chemical Society, vol. 142, no. 15, Mar. 2020, pp. 7218-7224. https://doi.org/10.1021%2Fjacs.0c02406.
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