Journal of the American Chemical Society, volume 139, issue 33, pages 11309-11312

Cascade Polymerization via Controlled Tandem Olefin Metathesis/Metallotropic 1,3-Shift Reactions for the Synthesis of Fully Conjugated Polyenynes

Cheol Kang ¹

Hyeon Park ¹

JIN KYUNG LEE ¹

Tae Lim Choi ¹

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Department of Chemistry, Seoul National University, Seoul 08826, Korea |

Publication type: Journal Article

Publication date: 2017-08-08

American Chemical Society (ACS)

Journal: Journal of the American Chemical Society

scimago Q1

SJR: 5.489

CiteScore: 24.4

Impact factor: 14.4

ISSN: 00027863, 15205126

DOI: 10.1021/jacs.7b04913

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PubMed ID: 28787148

General Chemistry

Catalysis

Biochemistry

Colloid and Surface Chemistry

Abstract

We demonstrate the first example of cascade polymerization by combining olefin metathesis and metallotropic 1,3-shift reactions to form unique conjugated polyenynes. Rational design of monomers enabled controlled polymerization, and kinetic investigation of the polymerization mechanism was conducted.

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Publisher

American Chemical Society (ACS)

Journal

Journal of the American Chemical Society

scimago Q1

SJR

5.489

CiteScore

24.4

Impact factor

14.4

ISSN

00027863 (Print)

15205126 (Electronic)

Cascade Polymerization via Controlled Tandem Olefin Metathesis/Metallotropic 1,3-Shift Reactions for the Synthesis of Fully Conjugated Polyenynes

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