volume 57 issue 7 pages 2047-2052

Solid-state and solution conformational analysis of tartrate-derived 1,3-dioxolanes and 1,3,2-dioxaborolanes

William R Roush
Andrew M Ratz
Jill A. Jablonowski
Publication typeJournal Article
Publication date1992-03-01
scimago Q2
wos Q1
SJR0.737
CiteScore6.1
Impact factor3.6
ISSN00223263, 15206904
Organic Chemistry
Abstract
Solid-state (X-ray) and solution conformational analyses of tartrate ester derived 1,3-dioxolanes and 1,3,2-dioxaborolanes are described. The solid-state conformation of dimethyl benzylidenetartrate (5) was found to be one in which the two carbomethoxy groups are pseudaxial and the ester carbonyls eclipse the adjacent dioxolane C-O bonds. This parallels exactly the conformation previously proposed for the 1,3,2-dioxaborolane unit in the transition state of the reactions of tartrate ester modified allylboronates 1-3 and aldehydes
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Roush W. R., Ratz A. M., Jablonowski J. A. Solid-state and solution conformational analysis of tartrate-derived 1,3-dioxolanes and 1,3,2-dioxaborolanes // Journal of Organic Chemistry. 1992. Vol. 57. No. 7. pp. 2047-2052.
GOST all authors (up to 50) Copy
Roush W. R., Ratz A. M., Jablonowski J. A. Solid-state and solution conformational analysis of tartrate-derived 1,3-dioxolanes and 1,3,2-dioxaborolanes // Journal of Organic Chemistry. 1992. Vol. 57. No. 7. pp. 2047-2052.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/jo00033a027
UR - https://doi.org/10.1021/jo00033a027
TI - Solid-state and solution conformational analysis of tartrate-derived 1,3-dioxolanes and 1,3,2-dioxaborolanes
T2 - Journal of Organic Chemistry
AU - Roush, William R
AU - Ratz, Andrew M
AU - Jablonowski, Jill A.
PY - 1992
DA - 1992/03/01
PB - American Chemical Society (ACS)
SP - 2047-2052
IS - 7
VL - 57
SN - 0022-3263
SN - 1520-6904
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{1992_Roush,
author = {William R Roush and Andrew M Ratz and Jill A. Jablonowski},
title = {Solid-state and solution conformational analysis of tartrate-derived 1,3-dioxolanes and 1,3,2-dioxaborolanes},
journal = {Journal of Organic Chemistry},
year = {1992},
volume = {57},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/jo00033a027},
number = {7},
pages = {2047--2052},
doi = {10.1021/jo00033a027}
}
MLA
Cite this
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Roush, William R., et al. “Solid-state and solution conformational analysis of tartrate-derived 1,3-dioxolanes and 1,3,2-dioxaborolanes.” Journal of Organic Chemistry, vol. 57, no. 7, Mar. 1992, pp. 2047-2052. https://doi.org/10.1021/jo00033a027.