Spatially-directed oxidation of gold nanoparticles by Au(III)-CTAB complexes.
Тип публикации: Journal Article
Дата публикации: 2005-07-13
scimago Q1
wos Q3
white level БС2
SJR: 0.742
CiteScore: 5.3
Impact factor: 2.9
ISSN: 15206106, 15205207, 10895647
PubMed ID:
16852790
Materials Chemistry
Surfaces, Coatings and Films
Physical and Theoretical Chemistry
Краткое описание
Gold nanoparticles are readily oxidized by Au(III) in the presence of cetyl-trimethylammonium bromide (CTAB). Oxidation occurs preferentially at surface sites with higher curvature. Conversely, oxidation with cyanide ions in the absence of CTAB leads to uniform oxidation over the whole surface. Examples of the spatially directed oxidation are provided using large, irregular spheres, nanocubes, and nanorods. We conclude that the mechanism of oxidation depends on whether the oxidant is attached to CTAB micelles. It is postulated that the CTAB micelles approach the nanoparticles preferentially at the tips, leading to spatially directed oxidation.
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ГОСТ
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Rodríguez Fernández J. et al. Spatially-directed oxidation of gold nanoparticles by Au(III)-CTAB complexes. // Journal of Physical Chemistry B. 2005. Vol. 109. No. 30. pp. 14257-14261.
ГОСТ со всеми авторами (до 50)
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Rodríguez Fernández J., Pérez-Juste J., Mulvaney P., Liz-Marzan L. Spatially-directed oxidation of gold nanoparticles by Au(III)-CTAB complexes. // Journal of Physical Chemistry B. 2005. Vol. 109. No. 30. pp. 14257-14261.
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RIS
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TY - JOUR
DO - 10.1021/jp052516g
UR - https://doi.org/10.1021/jp052516g
TI - Spatially-directed oxidation of gold nanoparticles by Au(III)-CTAB complexes.
T2 - Journal of Physical Chemistry B
AU - Rodríguez Fernández, Jessica
AU - Pérez-Juste, Jorge
AU - Mulvaney, Paul
AU - Liz-Marzan, Luis
PY - 2005
DA - 2005/07/13
PB - American Chemical Society (ACS)
SP - 14257-14261
IS - 30
VL - 109
PMID - 16852790
SN - 1520-6106
SN - 1520-5207
SN - 1089-5647
ER -
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BibTex (до 50 авторов)
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@article{2005_Rodríguez Fernández,
author = {Jessica Rodríguez Fernández and Jorge Pérez-Juste and Paul Mulvaney and Luis Liz-Marzan},
title = {Spatially-directed oxidation of gold nanoparticles by Au(III)-CTAB complexes.},
journal = {Journal of Physical Chemistry B},
year = {2005},
volume = {109},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/jp052516g},
number = {30},
pages = {14257--14261},
doi = {10.1021/jp052516g}
}
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MLA
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Rodríguez Fernández, Jessica, et al. “Spatially-directed oxidation of gold nanoparticles by Au(III)-CTAB complexes..” Journal of Physical Chemistry B, vol. 109, no. 30, Jul. 2005, pp. 14257-14261. https://doi.org/10.1021/jp052516g.
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