Organic Letters, volume 3, issue 21, pages 3345-3347

Nickel-Promoted Alkylative or Arylative Carboxylation of Alkynes

Masanori TAKIMOTO ¹

KAZUYA SHIMIZU ¹

Miwako MORI ¹

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Graduate School of Pharmaceutical Scieneces, Hokkaido University, Sapporo 060-0812, Japan |

Publication type: Journal Article

Publication date: 2001-09-27

American Chemical Society (ACS)

Journal: Organic Letters

scimago Q1

SJR: 1.245

CiteScore: 9.3

Impact factor: 4.9

ISSN: 15237060, 15237052

DOI: 10.1021/ol016585z

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PubMed ID: 11594830

Organic Chemistry

Biochemistry

Physical and Theoretical Chemistry

Abstract

[reaction: see text]. Nickel-promoted alkylative or arylative carboxylation of terminal alkynes via a carbon dioxide fixation process was investigated. In the presence of a stoichiometric amount of a zero-valent nickel complex, the reaction of alkynes with CO2 gave a nickelacycle, which was reacted with various organozinc reagents under very mild conditions to provide beta,beta'-disubstituted, alpha,beta-unsaturated carboxylic acids in a highly regio- and stereoselective manner.

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TAKIMOTO M., SHIMIZU K., MORI M. Nickel-Promoted Alkylative or Arylative Carboxylation of Alkynes // Organic Letters. 2001. Vol. 3. No. 21. pp. 3345-3347.

GOST all authors (up to 50) Copy

TAKIMOTO M., SHIMIZU K., MORI M. Nickel-Promoted Alkylative or Arylative Carboxylation of Alkynes // Organic Letters. 2001. Vol. 3. No. 21. pp. 3345-3347.

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RIS Copy

TY - JOUR

DO - 10.1021/ol016585z

UR - https://doi.org/10.1021/ol016585z

TI - Nickel-Promoted Alkylative or Arylative Carboxylation of Alkynes

T2 - Organic Letters

AU - TAKIMOTO, Masanori

AU - SHIMIZU, KAZUYA

AU - MORI, Miwako

PY - 2001

DA - 2001/09/27

PB - American Chemical Society (ACS)

SP - 3345-3347

IS - 21

VL - 3

PMID - 11594830

SN - 1523-7060

SN - 1523-7052

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2001_TAKIMOTO,

author = {Masanori TAKIMOTO and KAZUYA SHIMIZU and Miwako MORI},

title = {Nickel-Promoted Alkylative or Arylative Carboxylation of Alkynes},

journal = {Organic Letters},

year = {2001},

volume = {3},

publisher = {American Chemical Society (ACS)},

month = {sep},

url = {https://doi.org/10.1021/ol016585z},

number = {21},

pages = {3345--3347},

doi = {10.1021/ol016585z}

}

MLA

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TAKIMOTO, Masanori, et al. “Nickel-Promoted Alkylative or Arylative Carboxylation of Alkynes.” Organic Letters, vol. 3, no. 21, Sep. 2001, pp. 3345-3347. https://doi.org/10.1021/ol016585z.

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Publisher

American Chemical Society (ACS)

Journal

Organic Letters

scimago Q1

SJR

1.245

CiteScore

9.3

Impact factor

4.9

ISSN

15237060 (Print)

15237052 (Electronic)