Organic Letters, volume 12, issue 17, pages 3729-3731
Cyclic Alternating Ring-Opening Metathesis Polymerization (CAROMP). Rapid Access to Functionalized Cyclic Polymers
Airong Song
1
,
Kathlyn A Parker
1
,
Nicole S. Sampson
1
Publication type: Journal Article
Publication date: 2010-08-04
Journal:
Organic Letters
scimago Q1
SJR: 1.245
CiteScore: 9.3
Impact factor: 4.9
ISSN: 15237060, 15237052
PubMed ID:
20684538
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
Catalysis of alternating ROMP with (H(2)IMes)Cl(2)Ru=CHPh(OiPr), the second generation Hoveyda-Grubbs catalyst, provided an entirely cyclic alternating polymer. Conditions for the cyclic AROMP were used to prepare a polymer in which one of the repeat units bore a primary alkyl chloride that was used for further elaboration.
Found
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