Efficient One-Pot Synthesis of α,β-Unsaturated Carbyne Complexes fac-[RuX3{⋮CC(H)CR2}(dppf)] (X = Cl, Br; R = Aryl, Alkyl; dppf = 1,1‘-Bis(diphenylphosphino)ferrocene)
Publication type: Journal Article
Publication date: 2005-05-18
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Alkenyl-carbyne complexes fac-[RuX3{⋮CC(H)CR2}(dppf)] (X = Cl, Br; R = Ph, iPr or CR2 = C13H8) (2a−c, 3a−c) have been prepared by reaction of the bis(allyl)-ruthenium(II) derivative [Ru(η3-2-C3H4Me)2(dppf)] (1) with the appropriate propargylic alcohol HC⋮CCR2(OH) in the presence of 3.5 equiv of the corresponding hydrogen halide HX. The structure of compounds fac-[RuCl3{⋮CC(H)CR2}(dppf)] (R = Ph (2a) and iPr (2c)) has been confirmed by X-ray crystallography. Structural parameters within the alkenyl-carbyne chain in 2a,c suggest an important contribution of the zwitterionic vinylidene canonical form fac-[RuCl3{CC(H)-CR2}(dppf)]. Formation of complexes 2,3a−c involves the 1,3-addition of HX to the corresponding dinuclear allenylidene intermediates [{RuX(μ-X)(CCCR2)(dppf)}2]. Such allenylidene complexes, i.e., [{RuX(μ-X)(CCCR2)(dppf)}2] (X = Cl, Br; R = Ph or CR2 = C13H8) (4a,b, 5a,b), have been prepared and characterized by treatment of fac-[RuX3{⋮CC(H)CR2}(dppf)] (X = Cl, Br; R = Ph or CR2 = C13H8) (2a,b, 3...
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Cadierno V. et al. Efficient One-Pot Synthesis of α,β-Unsaturated Carbyne Complexes fac-[RuX3{⋮CC(H)CR2}(dppf)] (X = Cl, Br; R = Aryl, Alkyl; dppf = 1,1‘-Bis(diphenylphosphino)ferrocene) // Organometallics. 2005. Vol. 24. No. 13. pp. 3111-3117.
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Cadierno V., Diez J. G., Garcı́a-Garrido S. E., Gimeno J. Efficient One-Pot Synthesis of α,β-Unsaturated Carbyne Complexes fac-[RuX3{⋮CC(H)CR2}(dppf)] (X = Cl, Br; R = Aryl, Alkyl; dppf = 1,1‘-Bis(diphenylphosphino)ferrocene) // Organometallics. 2005. Vol. 24. No. 13. pp. 3111-3117.
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TY - JOUR
DO - 10.1021/om050204u
UR - https://doi.org/10.1021/om050204u
TI - Efficient One-Pot Synthesis of α,β-Unsaturated Carbyne Complexes fac-[RuX3{⋮CC(H)CR2}(dppf)] (X = Cl, Br; R = Aryl, Alkyl; dppf = 1,1‘-Bis(diphenylphosphino)ferrocene)
T2 - Organometallics
AU - Cadierno, Victorio
AU - Diez, Josefina Gonzalez
AU - Garcı́a-Garrido, Sergio E
AU - Gimeno, José
PY - 2005
DA - 2005/05/18
PB - American Chemical Society (ACS)
SP - 3111-3117
IS - 13
VL - 24
SN - 0276-7333
SN - 1520-6041
ER -
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@article{2005_Cadierno,
author = {Victorio Cadierno and Josefina Gonzalez Diez and Sergio E Garcı́a-Garrido and José Gimeno},
title = {Efficient One-Pot Synthesis of α,β-Unsaturated Carbyne Complexes fac-[RuX3{⋮CC(H)CR2}(dppf)] (X = Cl, Br; R = Aryl, Alkyl; dppf = 1,1‘-Bis(diphenylphosphino)ferrocene)},
journal = {Organometallics},
year = {2005},
volume = {24},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/om050204u},
number = {13},
pages = {3111--3117},
doi = {10.1021/om050204u}
}
Cite this
MLA
Copy
Cadierno, Victorio, et al. “Efficient One-Pot Synthesis of α,β-Unsaturated Carbyne Complexes fac-[RuX3{⋮CC(H)CR2}(dppf)] (X = Cl, Br; R = Aryl, Alkyl; dppf = 1,1‘-Bis(diphenylphosphino)ferrocene).” Organometallics, vol. 24, no. 13, May. 2005, pp. 3111-3117. https://doi.org/10.1021/om050204u.