Organometallics, volume 25, issue 24, pages 5696-5698

Anionic Ligand Exchange in Hoveyda−Grubbs Ruthenium(II) Benzylidenes

Kiyotaka Tanaka ¹

Volker P.W Böhm ¹

D CHADWICK ¹

Michael Roeper ¹

D. Christopher Braddock ¹

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Department of Chemistry, Imperial College London, London, SW7 2AZ U.K., Basic Chemicals Research, BASF Aktiengesellschaft, Ludwigshafen, Germany, and Department of Chemical Engineering, Imperial College London, South Kensington, London SW7 2AZ, U.K. |

Publication type: Journal Article

Publication date: 2006-10-18

American Chemical Society (ACS)

Journal: Organometallics

scimago Q1

SJR: 0.654

CiteScore: 5.6

Impact factor: 2.5

ISSN: 02767333, 15206041

DOI: 10.1021/om060913n

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Organic Chemistry

Inorganic Chemistry

Physical and Theoretical Chemistry

Abstract

A series of Hoveyda−Grubbs benzylidenes, Ru(X)2(IMesH2)(CH-2-(2-PrO)C6H4) (X = Cl, Br, CF3CO2, C2F5CO2; IMesH2 = 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene) were demonstrated to undergo intermolecular anionic ligand exchange when mixed. The implication is that anionic ligand exchange is occurring between identical ruthenium benzylidenes at all times in solution. A mechanism involving bridged dimers is invoked.

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CITATIONS

48 Total citations

1 Recent citation

5.31 Field Citation Ratio

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Tanaka K. et al. Anionic Ligand Exchange in Hoveyda−Grubbs Ruthenium(II) Benzylidenes // Organometallics. 2006. Vol. 25. No. 24. pp. 5696-5698.

GOST all authors (up to 50) Copy

Tanaka K., Böhm V. P., CHADWICK D., Roeper M., Braddock D. C. Anionic Ligand Exchange in Hoveyda−Grubbs Ruthenium(II) Benzylidenes // Organometallics. 2006. Vol. 25. No. 24. pp. 5696-5698.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1021/om060913n

UR - https://doi.org/10.1021/om060913n

TI - Anionic Ligand Exchange in Hoveyda−Grubbs Ruthenium(II) Benzylidenes

T2 - Organometallics

AU - Tanaka, Kiyotaka

AU - Böhm, Volker P.W

AU - CHADWICK, D

AU - Roeper, Michael

AU - Braddock, D. Christopher

PY - 2006

DA - 2006/10/18

PB - American Chemical Society (ACS)

SP - 5696-5698

IS - 24

VL - 25

SN - 0276-7333

SN - 1520-6041

ER -

BibTex |

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@article{2006_Tanaka,

author = {Kiyotaka Tanaka and Volker P.W Böhm and D CHADWICK and Michael Roeper and D. Christopher Braddock},

title = {Anionic Ligand Exchange in Hoveyda−Grubbs Ruthenium(II) Benzylidenes},

journal = {Organometallics},

year = {2006},

volume = {25},

publisher = {American Chemical Society (ACS)},

month = {oct},

url = {https://doi.org/10.1021/om060913n},

number = {24},

pages = {5696--5698},

doi = {10.1021/om060913n}

}

MLA

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MLA Copy

Tanaka, Kiyotaka, et al. “Anionic Ligand Exchange in Hoveyda−Grubbs Ruthenium(II) Benzylidenes.” Organometallics, vol. 25, no. 24, Oct. 2006, pp. 5696-5698. https://doi.org/10.1021/om060913n.

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Publisher

American Chemical Society (ACS)

Journal

Organometallics

scimago Q1

SJR

0.654

CiteScore

5.6

Impact factor

2.5

ISSN

02767333 (Print)

15206041 (Electronic)