Synthesis, Coordination Behavior, and Use in Asymmetric Hydrogenations of Walphos-Type Ligands
Yaping Wang
1
,
Thomas Sturm
1
,
Marianne Steurer
1
,
Vladimir B. Arion
1
,
K. Mereiter
1
,
Felix Spindler
1
,
Walter Weissensteiner
1
1
Institute of Organic Chemistry, University of Vienna, Währinger Strasse 38, A-1090 Vienna, Austria, Institute of Inorganic Chemistry, University of Vienna, Währinger Strasse 42, A-1090 Vienna, Austria, Institute of Chemical Technologies and Analytics, Vienna University of Technology, Getreidemarkt 9/164SC, A-1060 Vienna, Austria, and Solvias AG, Catalysis Research, P.O. Box, CH-4002 Basel, Switzerland
|
Publication type: Journal Article
Publication date: 2008-02-19
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
A total of nine Walphos-type diphosphine ligands, all of which have a ferrocenyl-aryl backbone, have been synthesized, characterized, and tested in asymmetric ruthenium-, rhodium-, and iridium-catalyzed hydrogenations of alkenes, ketones, and one imine. Ruthenium- and rhodium-mediated hydrogenations of alkenes and ketones gave enantioselectivities of up to 95% and 97% ee, respectively. Ligand tuning was attempted by variation of the phosphorus-bound aryl and alkyl substituents and by attaching electron-donating or electron-withdrawing substituents to the backbone phenyl ring. Dichloropalladium(II) complexes of five ligands were synthesized, and in four cases the molecular structures were studied in solution as well as in the solid state.
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Wang Y. et al. Synthesis, Coordination Behavior, and Use in Asymmetric Hydrogenations of Walphos-Type Ligands // Organometallics. 2008. Vol. 27. No. 6. pp. 1119-1127.
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Wang Y., Sturm T., Steurer M., Arion V. B., Mereiter K., Spindler F., Weissensteiner W. Synthesis, Coordination Behavior, and Use in Asymmetric Hydrogenations of Walphos-Type Ligands // Organometallics. 2008. Vol. 27. No. 6. pp. 1119-1127.
Cite this
RIS
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TY - JOUR
DO - 10.1021/om701103d
UR - https://doi.org/10.1021/om701103d
TI - Synthesis, Coordination Behavior, and Use in Asymmetric Hydrogenations of Walphos-Type Ligands
T2 - Organometallics
AU - Wang, Yaping
AU - Sturm, Thomas
AU - Steurer, Marianne
AU - Arion, Vladimir B.
AU - Mereiter, K.
AU - Spindler, Felix
AU - Weissensteiner, Walter
PY - 2008
DA - 2008/02/19
PB - American Chemical Society (ACS)
SP - 1119-1127
IS - 6
VL - 27
SN - 0276-7333
SN - 1520-6041
ER -
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BibTex (up to 50 authors)
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@article{2008_Wang,
author = {Yaping Wang and Thomas Sturm and Marianne Steurer and Vladimir B. Arion and K. Mereiter and Felix Spindler and Walter Weissensteiner},
title = {Synthesis, Coordination Behavior, and Use in Asymmetric Hydrogenations of Walphos-Type Ligands},
journal = {Organometallics},
year = {2008},
volume = {27},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/om701103d},
number = {6},
pages = {1119--1127},
doi = {10.1021/om701103d}
}
Cite this
MLA
Copy
Wang, Yaping, et al. “Synthesis, Coordination Behavior, and Use in Asymmetric Hydrogenations of Walphos-Type Ligands.” Organometallics, vol. 27, no. 6, Feb. 2008, pp. 1119-1127. https://doi.org/10.1021/om701103d.