Organometallics, volume 27, issue 5, pages 811-813
A Thermally Switchable Latent Ruthenium Olefin Metathesis Catalyst
Amos Ben-Asuly
1
,
Eyal Tzur
1
,
Charles E. Diesendruck
1
,
Mark Sigalov
1
,
Israel Goldberg
1
,
Publication type: Journal Article
Publication date: 2008-02-06
Journal:
Organometallics
scimago Q1
SJR: 0.654
CiteScore: 5.6
Impact factor: 2.5
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The synthesis and characterization of a cis-dichloro sulfur chelated olefin metathesis catalyst is presented. The catalyst was extremely stable at room temperature in solution under ambient conditions and was shown to exhibit a thermo-switchable behavior for ring-closing olefin metathesis of diethyl diallylmalonate, being active at 80 °C and inactive at room temperature.
Found
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.