Organometallics, volume 27, issue 5, pages 811-813

A Thermally Switchable Latent Ruthenium Olefin Metathesis Catalyst

Publication typeJournal Article
Publication date2008-02-06
Journal: Organometallics
scimago Q1
SJR0.654
CiteScore5.6
Impact factor2.5
ISSN02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The synthesis and characterization of a cis-dichloro sulfur chelated olefin metathesis catalyst is presented. The catalyst was extremely stable at room temperature in solution under ambient conditions and was shown to exhibit a thermo-switchable behavior for ring-closing olefin metathesis of diethyl diallylmalonate, being active at 80 °C and inactive at room temperature.
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