Metal-Catalyzed Decaborane−Alkyne Hydroboration Reactions: Efficient Routes to Alkenyldecaboranes
Publication type: Journal Article
Publication date: 2010-04-05
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
20222715
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Transition-metal-catalyzed decaborane-alkyne hydroboration reactions have been developed that provide high-yield routes to the previously unknown di- and monoalkenyldecaboranes. These alkenyl derivatives should be easily modified starting materials for many biomedical and/or materials applications. Unusual catalyst product selectivity was observed that suggests quite different mechanistic steps, with the reactions catalyzed by the [RuCl(2)(p-cymene)](2) and [Cp*IrCl(2)](2) complexes giving the beta-E alkenyldecaboranes and the corresponding reactions with the [RuI(2)(p-cymene)](2) complex giving the alpha-alkenyldecaborane isomers.
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Total citations:
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Citations from 2024:
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(10.53%)
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GOST
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Chatterjee S. Metal-Catalyzed Decaborane−Alkyne Hydroboration Reactions: Efficient Routes to Alkenyldecaboranes // Inorganic Chemistry. 2010. Vol. 49. No. 7. pp. 3095-3097.
GOST all authors (up to 50)
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Chatterjee S. Metal-Catalyzed Decaborane−Alkyne Hydroboration Reactions: Efficient Routes to Alkenyldecaboranes // Inorganic Chemistry. 2010. Vol. 49. No. 7. pp. 3095-3097.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ic100323e
UR - https://doi.org/10.1021/ic100323e
TI - Metal-Catalyzed Decaborane−Alkyne Hydroboration Reactions: Efficient Routes to Alkenyldecaboranes
T2 - Inorganic Chemistry
AU - Chatterjee, Shahana
PY - 2010
DA - 2010/04/05
PB - American Chemical Society (ACS)
SP - 3095-3097
IS - 7
VL - 49
PMID - 20222715
SN - 0020-1669
SN - 1520-510X
ER -
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BibTex (up to 50 authors)
Copy
@article{2010_Chatterjee,
author = {Shahana Chatterjee},
title = {Metal-Catalyzed Decaborane−Alkyne Hydroboration Reactions: Efficient Routes to Alkenyldecaboranes},
journal = {Inorganic Chemistry},
year = {2010},
volume = {49},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/ic100323e},
number = {7},
pages = {3095--3097},
doi = {10.1021/ic100323e}
}
Cite this
MLA
Copy
Chatterjee, Shahana, et al. “Metal-Catalyzed Decaborane−Alkyne Hydroboration Reactions: Efficient Routes to Alkenyldecaboranes.” Inorganic Chemistry, vol. 49, no. 7, Apr. 2010, pp. 3095-3097. https://doi.org/10.1021/ic100323e.