Role of water and carbonates in photocatalytic transformation of CO2 to CH4 on titania.
Nada M. Dimitrijevic
1
,
Baiju Vijayan
2
,
Oleg G. Poluektov
3
,
Tijana Rajh
3
,
Kimberly Gray
2
,
Haiying He
3
,
Publication type: Journal Article
Publication date: 2011-02-24
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
21348527
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
Using the electron paramagnetic resonance technique, we have elucidated the multiple roles of water and carbonates in the overall photocatalytic reduction of carbon dioxide to methane over titania nanoparticles. The formation of H atoms (reduction product) and (•)OH radicals (oxidation product) from water, and CO(3)(-) radical anions (oxidation product) from carbonates, was detected in CO(2)-saturated titania aqueous dispersion under UV illumination. Additionally, methoxyl, (•)OCH(3), and methyl, (•)CH(3), radicals were identified as reaction intermediates. The two-electron, one-proton reaction proposed as an initial step in the reduction of CO(2) on the surface of TiO(2) is supported by the results of first-principles calculations.
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Total citations:
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Citations from 2024:
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GOST
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Dimitrijevic N. M. et al. Role of water and carbonates in photocatalytic transformation of CO2 to CH4 on titania. // Journal of the American Chemical Society. 2011. Vol. 133. No. 11. pp. 3964-3971.
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Dimitrijevic N. M., Vijayan B., Poluektov O. G., Rajh T., Gray K., He H., Zapol P. Role of water and carbonates in photocatalytic transformation of CO2 to CH4 on titania. // Journal of the American Chemical Society. 2011. Vol. 133. No. 11. pp. 3964-3971.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ja108791u
UR - https://doi.org/10.1021/ja108791u
TI - Role of water and carbonates in photocatalytic transformation of CO2 to CH4 on titania.
T2 - Journal of the American Chemical Society
AU - Dimitrijevic, Nada M.
AU - Vijayan, Baiju
AU - Poluektov, Oleg G.
AU - Rajh, Tijana
AU - Gray, Kimberly
AU - He, Haiying
AU - Zapol, Peter
PY - 2011
DA - 2011/02/24
PB - American Chemical Society (ACS)
SP - 3964-3971
IS - 11
VL - 133
PMID - 21348527
SN - 0002-7863
SN - 1520-5126
ER -
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BibTex (up to 50 authors)
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@article{2011_Dimitrijevic,
author = {Nada M. Dimitrijevic and Baiju Vijayan and Oleg G. Poluektov and Tijana Rajh and Kimberly Gray and Haiying He and Peter Zapol},
title = {Role of water and carbonates in photocatalytic transformation of CO2 to CH4 on titania.},
journal = {Journal of the American Chemical Society},
year = {2011},
volume = {133},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/ja108791u},
number = {11},
pages = {3964--3971},
doi = {10.1021/ja108791u}
}
Cite this
MLA
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Dimitrijevic, Nada M., et al. “Role of water and carbonates in photocatalytic transformation of CO2 to CH4 on titania..” Journal of the American Chemical Society, vol. 133, no. 11, Feb. 2011, pp. 3964-3971. https://doi.org/10.1021/ja108791u.