Synthesis, Isolation, Characterization, and Reactivity of High-Energy Stereogenic-at-Ru Carbenes: Stereochemical Inversion through Olefin Metathesis and Other Pathways
Publication type: Journal Article
Publication date: 2012-07-20
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
22816554
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
The synthesis, isolation, purification (routine silica gel chromatography), and spectroscopic characterization of high-energy endo stereogenic-at-Ru complex isomers, generated by ring-opening/cross-metathesis (ROCM) reaction of the corresponding exo carbenes, are disclosed. We provide experimental evidence showing that an endo isomer can undergo thermal or Brønsted acid-catalyzed polytopal rearrangement, causing conversion to the energetically favored exo carbene.
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Metrics
44
Total citations:
44
Citations from 2024:
4
(9.1%)
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GOST
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Khan R. K. M. et al. Synthesis, Isolation, Characterization, and Reactivity of High-Energy Stereogenic-at-Ru Carbenes: Stereochemical Inversion through Olefin Metathesis and Other Pathways // Journal of the American Chemical Society. 2012. Vol. 134. No. 30. pp. 12438-12441.
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Khan R. K. M., Zhugralin A. R., Torker S., Obrien R. V., Lombardi P. J., Hoveyda A. H. Synthesis, Isolation, Characterization, and Reactivity of High-Energy Stereogenic-at-Ru Carbenes: Stereochemical Inversion through Olefin Metathesis and Other Pathways // Journal of the American Chemical Society. 2012. Vol. 134. No. 30. pp. 12438-12441.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ja3056722
UR - https://doi.org/10.1021/ja3056722
TI - Synthesis, Isolation, Characterization, and Reactivity of High-Energy Stereogenic-at-Ru Carbenes: Stereochemical Inversion through Olefin Metathesis and Other Pathways
T2 - Journal of the American Chemical Society
AU - Khan, R Kashif M
AU - Zhugralin, Adil R
AU - Torker, Sebastian
AU - Obrien, Robert V
AU - Lombardi, Pamela J.
AU - Hoveyda, Amir H.
PY - 2012
DA - 2012/07/20
PB - American Chemical Society (ACS)
SP - 12438-12441
IS - 30
VL - 134
PMID - 22816554
SN - 0002-7863
SN - 1520-5126
ER -
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BibTex (up to 50 authors)
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@article{2012_Khan,
author = {R Kashif M Khan and Adil R Zhugralin and Sebastian Torker and Robert V Obrien and Pamela J. Lombardi and Amir H. Hoveyda},
title = {Synthesis, Isolation, Characterization, and Reactivity of High-Energy Stereogenic-at-Ru Carbenes: Stereochemical Inversion through Olefin Metathesis and Other Pathways},
journal = {Journal of the American Chemical Society},
year = {2012},
volume = {134},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/ja3056722},
number = {30},
pages = {12438--12441},
doi = {10.1021/ja3056722}
}
Cite this
MLA
Copy
Khan, R. Kashif M., et al. “Synthesis, Isolation, Characterization, and Reactivity of High-Energy Stereogenic-at-Ru Carbenes: Stereochemical Inversion through Olefin Metathesis and Other Pathways.” Journal of the American Chemical Society, vol. 134, no. 30, Jul. 2012, pp. 12438-12441. https://doi.org/10.1021/ja3056722.