Journal of the American Chemical Society, volume 131, issue 1, pages 50-51
Activation of Carbon Nitride Solids by Protonation: Morphology Changes, Enhanced Ionic Conductivity, and Photoconduction Experiments
Publication type: Journal Article
Publication date: 2008-12-10
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 15
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
Covalently bonded carbon nitride materials (e.g., g-C(3)N(4)) have numerous potential applications ranging from semiconductors to fuel cells. But their solubility is poor, which makes characterization and processing difficult. Moreover, the chemistry of the as-synthesized carbon nitrides has been widely neglected. Here we report that some of these handicaps might be overcome by a controllable and reversible protonation. It was found that protonation not only provides better dispersion and exposes a high surface area for g-C(3)N(4) but also enables an adjustment of electronic band gaps and higher ionic conductivity. Recovery or deprotonation toward the original g-C(3)N(4) could be obtained by simple heating, which enables improved sintering but also a potential preservation of the higher surface area of the protonated material. This proton-enhanced sintering process allowed for the first time direct measurement of the photoconductivity of the material. By aid of protonation, other promising g-C(3)N(4) based hybrid composites could also be facilely obtained by simple counteranion exchange.
Top-30
Citations by journals
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6 publications, 0.85%
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Citations by publishers
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Elsevier
276 publications, 38.87%
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Royal Society of Chemistry (RSC)
143 publications, 20.14%
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Wiley
122 publications, 17.18%
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American Chemical Society (ACS)
79 publications, 11.13%
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Springer Nature
30 publications, 4.23%
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12 publications, 1.69%
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The Electrochemical Society
4 publications, 0.56%
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3 publications, 0.42%
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3 publications, 0.42%
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3 publications, 0.42%
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SAGE
2 publications, 0.28%
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Japan Society of Applied Physics
2 publications, 0.28%
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IOS Press
2 publications, 0.28%
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Beilstein-Institut
1 publication, 0.14%
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American Physical Society (APS)
1 publication, 0.14%
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The Chemical Society of Japan
1 publication, 0.14%
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Institution of Engineering and Technology (IET)
1 publication, 0.14%
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IWA Publishing
1 publication, 0.14%
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Nonferrous Metals Society of China
1 publication, 0.14%
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Taiwan Institute of Chemical Engineers
1 publication, 0.14%
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1 publication, 0.14%
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1 publication, 0.14%
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Walter de Gruyter
1 publication, 0.14%
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American Association for the Advancement of Science (AAAS)
1 publication, 0.14%
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Hans Publishers
1 publication, 0.14%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Zhang Y. et al. Activation of Carbon Nitride Solids by Protonation: Morphology Changes, Enhanced Ionic Conductivity, and Photoconduction Experiments // Journal of the American Chemical Society. 2008. Vol. 131. No. 1. pp. 50-51.
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Zhang Y., Thomas A., Antonietti M., Wang X. Activation of Carbon Nitride Solids by Protonation: Morphology Changes, Enhanced Ionic Conductivity, and Photoconduction Experiments // Journal of the American Chemical Society. 2008. Vol. 131. No. 1. pp. 50-51.
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TY - JOUR
DO - 10.1021/ja808329f
UR - https://doi.org/10.1021/ja808329f
TI - Activation of Carbon Nitride Solids by Protonation: Morphology Changes, Enhanced Ionic Conductivity, and Photoconduction Experiments
T2 - Journal of the American Chemical Society
AU - Zhang, Yuanjian
AU - Thomas, Arne
AU - Antonietti, Markus
AU - Wang, Xinchen
PY - 2008
DA - 2008/12/10 00:00:00
PB - American Chemical Society (ACS)
SP - 50-51
IS - 1
VL - 131
SN - 0002-7863
SN - 1520-5126
ER -
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@article{2008_Zhang,
author = {Yuanjian Zhang and Arne Thomas and Markus Antonietti and Xinchen Wang},
title = {Activation of Carbon Nitride Solids by Protonation: Morphology Changes, Enhanced Ionic Conductivity, and Photoconduction Experiments},
journal = {Journal of the American Chemical Society},
year = {2008},
volume = {131},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/ja808329f},
number = {1},
pages = {50--51},
doi = {10.1021/ja808329f}
}
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Zhang, Yuanjian, et al. “Activation of Carbon Nitride Solids by Protonation: Morphology Changes, Enhanced Ionic Conductivity, and Photoconduction Experiments.” Journal of the American Chemical Society, vol. 131, no. 1, Dec. 2008, pp. 50-51. https://doi.org/10.1021/ja808329f.