Visible-Light-Induced Reversible Complexation Mediated Living Radical Polymerization of Methacrylates with Organic Catalysts
Publication type: Journal Article
Publication date: 2012-12-18
scimago Q1
wos Q1
SJR: 1.352
CiteScore: 9.0
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
Photoinduced reversible complexation mediated polymerization (photo-RCMP) was developed as a new photoinduced living radical polymerization (LRP). It consisted of an alkyl iodide as a dormant species and an amine as a catalyst, using visible light at 350–600 nm. The amine catalysts include such common compounds as tributylamine. Mechanistically, the polymerization is induced by the photolysis of the dormant species and dormant species/catalyst complex, which frequently occurs as the main activation process. The polymer molecular weight and its distribution (Mw/Mn = 1.1–1.4) were well controlled in the polymerizations of methyl methacrylate and some functional methacrylates up to fairly high conversions in many cases. Perfectly no polymerization took place without photoirradiation, meaning that the system is an ideal photo “on”–“off” switchable system. The polymerization rate was also finely tunable by the external irradiation power. Attractive features of photo-RCMP include the uses of inexpensive compoun...
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165
Total citations:
165
Citations from 2024:
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(8.49%)
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Ohtsuki A., Goto A., Kaji H. Visible-Light-Induced Reversible Complexation Mediated Living Radical Polymerization of Methacrylates with Organic Catalysts // Macromolecules. 2012. Vol. 46. No. 1. pp. 96-102.
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Ohtsuki A., Goto A., Kaji H. Visible-Light-Induced Reversible Complexation Mediated Living Radical Polymerization of Methacrylates with Organic Catalysts // Macromolecules. 2012. Vol. 46. No. 1. pp. 96-102.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ma302244j
UR - https://doi.org/10.1021/ma302244j
TI - Visible-Light-Induced Reversible Complexation Mediated Living Radical Polymerization of Methacrylates with Organic Catalysts
T2 - Macromolecules
AU - Ohtsuki, Akimichi
AU - Goto, Atsushi
AU - Kaji, Hironori
PY - 2012
DA - 2012/12/18
PB - American Chemical Society (ACS)
SP - 96-102
IS - 1
VL - 46
SN - 0024-9297
SN - 1520-5835
ER -
Cite this
BibTex (up to 50 authors)
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@article{2012_Ohtsuki,
author = {Akimichi Ohtsuki and Atsushi Goto and Hironori Kaji},
title = {Visible-Light-Induced Reversible Complexation Mediated Living Radical Polymerization of Methacrylates with Organic Catalysts},
journal = {Macromolecules},
year = {2012},
volume = {46},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/ma302244j},
number = {1},
pages = {96--102},
doi = {10.1021/ma302244j}
}
Cite this
MLA
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Ohtsuki, Akimichi, et al. “Visible-Light-Induced Reversible Complexation Mediated Living Radical Polymerization of Methacrylates with Organic Catalysts.” Macromolecules, vol. 46, no. 1, Dec. 2012, pp. 96-102. https://doi.org/10.1021/ma302244j.