Remarkable Effect of Halogens on Catalytic Activities of Thiolato-Bridged Diruthenium Complexes in Propargylic Substitution Reactions
Publication type: Journal Article
Publication date: 2009-01-29
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Thiolato-bridged dibromo- and diiododiruthenium complexes [{Cp*RuX(μ-SR)}2] (X = Br, I; R = Me, iPr) have been prepared and characterized by X-ray analysis. Examination of their catalytic activity in propargylic substitution reactions of 1-phenyl-2-propyn-1-ol with some nucleophiles has revealed that the complexes [{Cp*RuX(μ-SiPr)}2] (X = Br, I) work as catalysts but less effectively in comparison with the well-investigated dichloride analogue [{Cp*RuCl(μ-SiPr)}2].
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Tanabe Y. et al. Remarkable Effect of Halogens on Catalytic Activities of Thiolato-Bridged Diruthenium Complexes in Propargylic Substitution Reactions // Organometallics. 2009. Vol. 28. No. 4. pp. 1138-1142.
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Tanabe Y., Kanao K., Miyake Y., Nishibayashi Y. Remarkable Effect of Halogens on Catalytic Activities of Thiolato-Bridged Diruthenium Complexes in Propargylic Substitution Reactions // Organometallics. 2009. Vol. 28. No. 4. pp. 1138-1142.
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RIS
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TY - JOUR
DO - 10.1021/om8011079
UR - https://doi.org/10.1021/om8011079
TI - Remarkable Effect of Halogens on Catalytic Activities of Thiolato-Bridged Diruthenium Complexes in Propargylic Substitution Reactions
T2 - Organometallics
AU - Tanabe, Yoshiaki
AU - Kanao, Keiichiro
AU - Miyake, Yoshihiro
AU - Nishibayashi, Yoshiaki
PY - 2009
DA - 2009/01/29
PB - American Chemical Society (ACS)
SP - 1138-1142
IS - 4
VL - 28
SN - 0276-7333
SN - 1520-6041
ER -
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BibTex (up to 50 authors)
Copy
@article{2009_Tanabe,
author = {Yoshiaki Tanabe and Keiichiro Kanao and Yoshihiro Miyake and Yoshiaki Nishibayashi},
title = {Remarkable Effect of Halogens on Catalytic Activities of Thiolato-Bridged Diruthenium Complexes in Propargylic Substitution Reactions},
journal = {Organometallics},
year = {2009},
volume = {28},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/om8011079},
number = {4},
pages = {1138--1142},
doi = {10.1021/om8011079}
}
Cite this
MLA
Copy
Tanabe, Yoshiaki, et al. “Remarkable Effect of Halogens on Catalytic Activities of Thiolato-Bridged Diruthenium Complexes in Propargylic Substitution Reactions.” Organometallics, vol. 28, no. 4, Jan. 2009, pp. 1138-1142. https://doi.org/10.1021/om8011079.