volume 29 issue 6 pages 1374-1378

Well-Defined N-Heterocyclic Carbene Based Ruthenium Catalysts for Direct Amide Synthesis from Alcohols and Amines

Publication typeJournal Article
Publication date2010-02-04
scimago Q2
wos Q1
SJR0.676
CiteScore5.1
Impact factor2.9
ISSN02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Well-defined N-heterocyclic carbene based ruthenium complexes were developed as highly active catalysts for direct amide synthesis from alcohols and amines. A catalytic amount of a base such as KOtBu was essential to initiate the catalytic cycle. Activity of the Ru complexes was comparable with the reported in situ Ru catalysts. These catalysts provided mechanistic insight suggesting a Ru hydride species as an active catalytic intermediate. The generation of the Ru hydride was critical for the amidation of free aldehydes.
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GOST Copy
Zhang Y. et al. Well-Defined N-Heterocyclic Carbene Based Ruthenium Catalysts for Direct Amide Synthesis from Alcohols and Amines // Organometallics. 2010. Vol. 29. No. 6. pp. 1374-1378.
GOST all authors (up to 50) Copy
Zhang Y., Chen C., Ghosh S., Li Y., Hong S. H. Well-Defined N-Heterocyclic Carbene Based Ruthenium Catalysts for Direct Amide Synthesis from Alcohols and Amines // Organometallics. 2010. Vol. 29. No. 6. pp. 1374-1378.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/om901020h
UR - https://doi.org/10.1021/om901020h
TI - Well-Defined N-Heterocyclic Carbene Based Ruthenium Catalysts for Direct Amide Synthesis from Alcohols and Amines
T2 - Organometallics
AU - Zhang, Yao
AU - Chen, C.L
AU - Ghosh, Subhash
AU - Li, Yongxin
AU - Hong, Soon Hyeok
PY - 2010
DA - 2010/02/04
PB - American Chemical Society (ACS)
SP - 1374-1378
IS - 6
VL - 29
SN - 0276-7333
SN - 1520-6041
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2010_Zhang,
author = {Yao Zhang and C.L Chen and Subhash Ghosh and Yongxin Li and Soon Hyeok Hong},
title = {Well-Defined N-Heterocyclic Carbene Based Ruthenium Catalysts for Direct Amide Synthesis from Alcohols and Amines},
journal = {Organometallics},
year = {2010},
volume = {29},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/om901020h},
number = {6},
pages = {1374--1378},
doi = {10.1021/om901020h}
}
MLA
Cite this
MLA Copy
Zhang, Yao, et al. “Well-Defined N-Heterocyclic Carbene Based Ruthenium Catalysts for Direct Amide Synthesis from Alcohols and Amines.” Organometallics, vol. 29, no. 6, Feb. 2010, pp. 1374-1378. https://doi.org/10.1021/om901020h.