Solvent-Induced Topological Diversity of Two Zn(II) Metal–Organic Frameworks and High Sensitivity in Recyclable Detection of Nitrobenzene
Тип публикации: Journal Article
Дата публикации: 2015-07-07
scimago Q2
wos Q1
БС1
SJR: 0.633
CiteScore: 5.6
Impact factor: 3.4
ISSN: 15287483, 15287505
General Chemistry
Condensed Matter Physics
General Materials Science
Краткое описание
The solvent-induced topological diversity and different framework stabilities were studied in two Zn(II) metal–organic frameworks (MOFs), {[Zn(L)]·DMA}n (1) and {[Zn(L)]·MeOH·0.5NMP}n (2) (H2L = 5-(4H-1,2,4-triazol-4-yl)isophthalic acid). Despite the fact that both of these MOFs are (3,6)-connected networks based on the same coordination environment of Zn(II) ions and the same coordination mode of the ligands, they adopt distinct nets with apo and rtl topologies, respectively, which originate from the template effects of the solvents and the conformational flexibility of the ligand. The two Zn(II) MOFs show remarkably different framework stability upon guest exchange due to their different topological structures. The luminescent properties of MOF 1 with different solvents have been studied in detail, which shows high sensitivity in the detection of nitrobenzene (NB). In addition, MOF 1 can be reused by simply washing with fresh solvent.
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Chen D. M. et al. Solvent-Induced Topological Diversity of Two Zn(II) Metal–Organic Frameworks and High Sensitivity in Recyclable Detection of Nitrobenzene // Crystal Growth and Design. 2015. Vol. 15. No. 8. pp. 3999-4004.
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Chen D. M., Ma X. Z., Shi W., Cheng P. Solvent-Induced Topological Diversity of Two Zn(II) Metal–Organic Frameworks and High Sensitivity in Recyclable Detection of Nitrobenzene // Crystal Growth and Design. 2015. Vol. 15. No. 8. pp. 3999-4004.
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TY - JOUR
DO - 10.1021/acs.cgd.5b00614
UR - https://doi.org/10.1021/acs.cgd.5b00614
TI - Solvent-Induced Topological Diversity of Two Zn(II) Metal–Organic Frameworks and High Sensitivity in Recyclable Detection of Nitrobenzene
T2 - Crystal Growth and Design
AU - Chen, Di Ming
AU - Ma, Xiao Zhou
AU - Shi, Wei
AU - Cheng, Peng
PY - 2015
DA - 2015/07/07
PB - American Chemical Society (ACS)
SP - 3999-4004
IS - 8
VL - 15
SN - 1528-7483
SN - 1528-7505
ER -
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@article{2015_Chen,
author = {Di Ming Chen and Xiao Zhou Ma and Wei Shi and Peng Cheng},
title = {Solvent-Induced Topological Diversity of Two Zn(II) Metal–Organic Frameworks and High Sensitivity in Recyclable Detection of Nitrobenzene},
journal = {Crystal Growth and Design},
year = {2015},
volume = {15},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/acs.cgd.5b00614},
number = {8},
pages = {3999--4004},
doi = {10.1021/acs.cgd.5b00614}
}
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MLA
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Chen, Di Ming, et al. “Solvent-Induced Topological Diversity of Two Zn(II) Metal–Organic Frameworks and High Sensitivity in Recyclable Detection of Nitrobenzene.” Crystal Growth and Design, vol. 15, no. 8, Jul. 2015, pp. 3999-4004. https://doi.org/10.1021/acs.cgd.5b00614.