Crystal Growth, HOMO–LUMO Engineering, and Charge Transfer Degree in Perylene-FxTCNQ (x = 1, 2, 4) Organic Charge Transfer Binary Compounds
Publication type: Journal Article
Publication date: 2016-04-14
scimago Q2
wos Q1
SJR: 0.633
CiteScore: 5.6
Impact factor: 3.4
ISSN: 15287483, 15287505
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
The methodologies of searching for novel organic charge transfer binary compounds and large-size crystal growth, in the case that only the two starting organic substances are known but the phase diagram is not known, the thermodynamic data of the binary compound are not known, and even the existence of new binary compounds is not known, were studied. Centimeter-long crystals of novel perylene-F1TCNQ, perylene-F2TCNQ, and perylene-F4TCNQ charge transfer binary compounds are obtained from the gas phase. Kinetically lowering the sublimation rate is the key factor for growing large-size charge transfer compound single crystals. Changing the number of fluorine atoms in FxTCNQ results in the variation of the electron affinity, which further changes the HOMO–LUMO of acceptor. Charge transfer degree is increased with increasing of fluorine atoms in the perylene-FxTCNQ system. Therefore, the structure, stoichiometry, and kind of donor and acceptor enable HOMO–LUMO engineering of the charge transfer compound and tu...
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155
Total citations:
155
Citations from 2025:
17
(10.97%)
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GOST
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Hu P. et al. Crystal Growth, HOMO–LUMO Engineering, and Charge Transfer Degree in Perylene-FxTCNQ (x = 1, 2, 4) Organic Charge Transfer Binary Compounds // Crystal Growth and Design. 2016. Vol. 16. No. 5. pp. 3019-3027.
GOST all authors (up to 50)
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Hu P., Du K., Wei F., Jiang H., Kloc C. Crystal Growth, HOMO–LUMO Engineering, and Charge Transfer Degree in Perylene-FxTCNQ (x = 1, 2, 4) Organic Charge Transfer Binary Compounds // Crystal Growth and Design. 2016. Vol. 16. No. 5. pp. 3019-3027.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.cgd.5b01675
UR - https://doi.org/10.1021/acs.cgd.5b01675
TI - Crystal Growth, HOMO–LUMO Engineering, and Charge Transfer Degree in Perylene-FxTCNQ (x = 1, 2, 4) Organic Charge Transfer Binary Compounds
T2 - Crystal Growth and Design
AU - Hu, Peng
AU - Du, Ke-Zhao
AU - Wei, F.
AU - Jiang, Hui
AU - Kloc, Christian
PY - 2016
DA - 2016/04/14
PB - American Chemical Society (ACS)
SP - 3019-3027
IS - 5
VL - 16
SN - 1528-7483
SN - 1528-7505
ER -
Cite this
BibTex (up to 50 authors)
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@article{2016_Hu,
author = {Peng Hu and Ke-Zhao Du and F. Wei and Hui Jiang and Christian Kloc},
title = {Crystal Growth, HOMO–LUMO Engineering, and Charge Transfer Degree in Perylene-FxTCNQ (x = 1, 2, 4) Organic Charge Transfer Binary Compounds},
journal = {Crystal Growth and Design},
year = {2016},
volume = {16},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/acs.cgd.5b01675},
number = {5},
pages = {3019--3027},
doi = {10.1021/acs.cgd.5b01675}
}
Cite this
MLA
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Hu, Peng, et al. “Crystal Growth, HOMO–LUMO Engineering, and Charge Transfer Degree in Perylene-FxTCNQ (x = 1, 2, 4) Organic Charge Transfer Binary Compounds.” Crystal Growth and Design, vol. 16, no. 5, Apr. 2016, pp. 3019-3027. https://doi.org/10.1021/acs.cgd.5b01675.