Pt/Pd and I/Br Isostructural Exchange Provides Formation of C–I···Pd, C–Br···Pt, and C–Br···Pd Metal-Involving Halogen Bonding
Publication type: Journal Article
Publication date: 2018-09-05
scimago Q2
wos Q1
SJR: 0.633
CiteScore: 5.6
Impact factor: 3.4
ISSN: 15287483, 15287505
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
Complexes trans-[MCl2(NCNMe2)2] (M = Pt 1, Pd 2) were cocrystallized with CHBr3 and CHI3, forming 1:2 adducts isomorphic with previously reported trans-[PtCl2(NCNMe2)2]·2CHI3. In all cases, the C–X···M (X = Br, I; M = Pd, Pt) metal-involving halogen bonding together with numerous chloride-halomethane halogen and hydrogen bonds were identified by single-crystal XRD experiments. Further DFT calculations and topological analysis of the electron density distribution within the framework of QTAIM method at the M06/DZP-DKH level of theory confirmed the existence of these interactions and their noncovalent nature. Estimated energies of such contacts vary from 1.6 to 3.1 kcal/mol.
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Total citations:
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Citations from 2025:
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(3.45%)
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Matveevskaya V. V. et al. Pt/Pd and I/Br Isostructural Exchange Provides Formation of C–I···Pd, C–Br···Pt, and C–Br···Pd Metal-Involving Halogen Bonding // Crystal Growth and Design. 2018. Vol. 18. No. 10. pp. 5973-5980.
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Matveevskaya V. V., Dabranskaya U., Ivanov D. M., Novikov A. S., Boyarskiy V. P. Pt/Pd and I/Br Isostructural Exchange Provides Formation of C–I···Pd, C–Br···Pt, and C–Br···Pd Metal-Involving Halogen Bonding // Crystal Growth and Design. 2018. Vol. 18. No. 10. pp. 5973-5980.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.cgd.8b00762
UR - https://doi.org/10.1021/acs.cgd.8b00762
TI - Pt/Pd and I/Br Isostructural Exchange Provides Formation of C–I···Pd, C–Br···Pt, and C–Br···Pd Metal-Involving Halogen Bonding
T2 - Crystal Growth and Design
AU - Matveevskaya, Vladislava V
AU - Dabranskaya, Uladzislava
AU - Ivanov, Daniil M
AU - Novikov, Alexander S.
AU - Boyarskiy, Vadim P
PY - 2018
DA - 2018/09/05
PB - American Chemical Society (ACS)
SP - 5973-5980
IS - 10
VL - 18
SN - 1528-7483
SN - 1528-7505
ER -
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@article{2018_Matveevskaya,
author = {Vladislava V Matveevskaya and Uladzislava Dabranskaya and Daniil M Ivanov and Alexander S. Novikov and Vadim P Boyarskiy},
title = {Pt/Pd and I/Br Isostructural Exchange Provides Formation of C–I···Pd, C–Br···Pt, and C–Br···Pd Metal-Involving Halogen Bonding},
journal = {Crystal Growth and Design},
year = {2018},
volume = {18},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/acs.cgd.8b00762},
number = {10},
pages = {5973--5980},
doi = {10.1021/acs.cgd.8b00762}
}
Cite this
MLA
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Matveevskaya, Vladislava V., et al. “Pt/Pd and I/Br Isostructural Exchange Provides Formation of C–I···Pd, C–Br···Pt, and C–Br···Pd Metal-Involving Halogen Bonding.” Crystal Growth and Design, vol. 18, no. 10, Sep. 2018, pp. 5973-5980. https://doi.org/10.1021/acs.cgd.8b00762.