Li2 Cu2 O(SO4 )2 : A possible electrode for sustainable li-based batteries showing a 4.7 V redox activity vs Li+/Li0
Meiling Sun
1
,
Gwenaelle Rousse
1, 2, 3
,
Matthieu Saubanère
3, 5
,
Marie-Liesse Doublet
3, 5
,
Juan Rodriguez-Carvajal
6
,
Gustaaf Van Tendeloo
4
,
Jean-Marie Tarascon
1, 2, 3
3
Тип публикации: Journal Article
Дата публикации: 2015-04-07
scimago Q1
wos Q1
БС1
SJR: 2.065
CiteScore: 12.0
Impact factor: 7.0
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Краткое описание
Li-ion batteries rely on the use of insertion positive electrodes with performances scaling with the redox potential of the 3D metals accompanying Li-uptake/removal. Although not commonly studied, the Cu2+/Cu3+ redox potential has been predicted from theoretical calculations to possibly offer a high operating voltage redox couple. We herein report the synthesis and crystal structure of a hitherto-unknown oxysulfate phase, Li2Cu2O(SO4)2, which contains infinite edge-sharing CuO4 chains and presents attractive electrochemical redox activity with respect to Li+/Li, namely amphoteric characteristics. Li2Cu2O(SO4)2 shows redox activity at 4.7 V vs Li+/Li0 corresponding to the oxidation of Cu2+ to Cu3+ enlisting ligand holes and associated with the reversible uptake-removal of 0.3 Li. Upon reduction, this compound reversibly uptakes ∼2 Li at an average potential of about 2.5 V vs Li+/Li0, associated with the Cu2+/Cu+ redox couple. The mechanism of the reactivity upon reduction is discussed in detail, with parti...
Найдено
Ничего не найдено, попробуйте изменить настройки фильтра.
Найдено
Ничего не найдено, попробуйте изменить настройки фильтра.
Топ-30
Журналы
|
1
2
3
4
5
|
|
|
Physical Review B
5 публикаций, 14.71%
|
|
|
Chemistry of Materials
4 публикации, 11.76%
|
|
|
Inorganic Chemistry
2 публикации, 5.88%
|
|
|
Journal of Materials Chemistry A
2 публикации, 5.88%
|
|
|
Mineralogical Magazine
1 публикация, 2.94%
|
|
|
Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials
1 публикация, 2.94%
|
|
|
Journal of Applied Crystallography
1 публикация, 2.94%
|
|
|
Materials
1 публикация, 2.94%
|
|
|
Physics and Chemistry of Minerals
1 публикация, 2.94%
|
|
|
Journal of Power Sources
1 публикация, 2.94%
|
|
|
Applied Surface Science
1 публикация, 2.94%
|
|
|
Journal of Energy Storage
1 публикация, 2.94%
|
|
|
Journal of Solid State Chemistry
1 публикация, 2.94%
|
|
|
ChemInform
1 публикация, 2.94%
|
|
|
Chemical Record
1 публикация, 2.94%
|
|
|
Israel Journal of Chemistry
1 публикация, 2.94%
|
|
|
Crystal Growth and Design
1 публикация, 2.94%
|
|
|
ACS Nano
1 публикация, 2.94%
|
|
|
CrystEngComm
1 публикация, 2.94%
|
|
|
Physical Chemistry Chemical Physics
1 публикация, 2.94%
|
|
|
Dalton Transactions
1 публикация, 2.94%
|
|
|
SciPost Physics
1 публикация, 2.94%
|
|
|
Geology of Ore Deposits
1 публикация, 2.94%
|
|
|
Chemical Engineering Journal
1 публикация, 2.94%
|
|
|
Journal of the Ceramic Society of Japan
1 публикация, 2.94%
|
|
|
1
2
3
4
5
|
Издатели
|
1
2
3
4
5
6
7
8
|
|
|
American Chemical Society (ACS)
8 публикаций, 23.53%
|
|
|
American Physical Society (APS)
5 публикаций, 14.71%
|
|
|
Elsevier
5 публикаций, 14.71%
|
|
|
Royal Society of Chemistry (RSC)
5 публикаций, 14.71%
|
|
|
Wiley
3 публикации, 8.82%
|
|
|
International Union of Crystallography (IUCr)
2 публикации, 5.88%
|
|
|
Mineralogical Society
1 публикация, 2.94%
|
|
|
MDPI
1 публикация, 2.94%
|
|
|
Springer Nature
1 публикация, 2.94%
|
|
|
Stichting SciPost
1 публикация, 2.94%
|
|
|
Pleiades Publishing
1 публикация, 2.94%
|
|
|
Ceramic Society of Japan
1 публикация, 2.94%
|
|
|
1
2
3
4
5
6
7
8
|
- Мы не учитываем публикации, у которых нет DOI.
- Статистика публикаций обновляется еженедельно.
Вы ученый?
Создайте профиль, чтобы получать персональные рекомендации коллег, конференций и новых статей.
Метрики
34
Всего цитирований:
34
Цитирований c 2024:
3
(8%)
Цитировать
ГОСТ |
RIS |
BibTex |
MLA
Цитировать
ГОСТ
Скопировать
Sun M. et al. Li2Cu2O(SO4)2: A possible electrode for sustainable li-based batteries showing a 4.7 V redox activity vs Li+/Li0 // Chemistry of Materials. 2015. Vol. 27. No. 8. pp. 3077-3087.
ГОСТ со всеми авторами (до 50)
Скопировать
Sun M., Rousse G., Abakumov A. M., Saubanère M., Doublet M., Rodriguez-Carvajal J., Van Tendeloo G., Tarascon J. Li2Cu2O(SO4)2: A possible electrode for sustainable li-based batteries showing a 4.7 V redox activity vs Li+/Li0 // Chemistry of Materials. 2015. Vol. 27. No. 8. pp. 3077-3087.
Цитировать
RIS
Скопировать
TY - JOUR
DO - 10.1021/acs.chemmater.5b00588
UR - https://doi.org/10.1021/acs.chemmater.5b00588
TI - Li2Cu2O(SO4)2: A possible electrode for sustainable li-based batteries showing a 4.7 V redox activity vs Li+/Li0
T2 - Chemistry of Materials
AU - Sun, Meiling
AU - Rousse, Gwenaelle
AU - Abakumov, Artem M.
AU - Saubanère, Matthieu
AU - Doublet, Marie-Liesse
AU - Rodriguez-Carvajal, Juan
AU - Van Tendeloo, Gustaaf
AU - Tarascon, Jean-Marie
PY - 2015
DA - 2015/04/07
PB - American Chemical Society (ACS)
SP - 3077-3087
IS - 8
VL - 27
SN - 0897-4756
SN - 1520-5002
ER -
Цитировать
BibTex (до 50 авторов)
Скопировать
@article{2015_Sun,
author = {Meiling Sun and Gwenaelle Rousse and Artem M. Abakumov and Matthieu Saubanère and Marie-Liesse Doublet and Juan Rodriguez-Carvajal and Gustaaf Van Tendeloo and Jean-Marie Tarascon},
title = {Li2Cu2O(SO4)2: A possible electrode for sustainable li-based batteries showing a 4.7 V redox activity vs Li+/Li0},
journal = {Chemistry of Materials},
year = {2015},
volume = {27},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/acs.chemmater.5b00588},
number = {8},
pages = {3077--3087},
doi = {10.1021/acs.chemmater.5b00588}
}
Цитировать
MLA
Скопировать
Sun, Meiling, et al. “Li2Cu2O(SO4)2: A possible electrode for sustainable li-based batteries showing a 4.7 V redox activity vs Li+/Li0.” Chemistry of Materials, vol. 27, no. 8, Apr. 2015, pp. 3077-3087. https://doi.org/10.1021/acs.chemmater.5b00588.
Профили