Chemistry of Materials, volume 27, issue 8, pages 3135-3142
Site Occupation of Ga and Al in Stabilized Cubic Li7–3(x+y)GaxAlyLa3Zr2O12 Garnets As Deduced from 27Al and 71Ga MAS NMR at Ultrahigh Magnetic Fields
Daniel Rettenwander
1
,
Julia Langer
2
,
Walter Schmidt
2
,
Christian Arrer
1
,
Kristopher J. Harris
3
,
Victor Terskikh
4
,
Martin Wilkening
2
,
G. Amthauer
1
1
Department
of Materials Research and Physics, University of Salzburg, 5020 Salzburg, Austria
|
3
4
Department
of Chemistry, University of Ottawa, Ottawa, Ontario K1N 6N5, Canada
|
Publication type: Journal Article
Publication date: 2015-04-14
Journal:
Chemistry of Materials
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 8.6
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
Li-containing garnets, which are stabilized in their cubic modification by doping with Al or Ga, show very high Li-ion conductivities. This property qualifies them to be used as solid electrolytes in advanced all-solid-state batteries. The relation between local structures and dynamic properties, however, is still not fully understood. Here, cubic mixed-doped Li7–3(x+y)GaxAlyLa3Zr2O12 garnet solid solutions with different portions of Al and Ga were synthesized. It turned out that the solubility of Ga is higher than that of Al; the evaluation of 42 different doping compositions indicated an increase of the lattice parameter a0 with increasing Ga content. 71Ga MAS NMR spectra recorded at 21.1 T revealed two 71Ga NMR resonances, corresponding to Ga occupying both the 24d (243 ppm) and 96h sites (193 ppm). This behavior, which has been observed for the first time in this study, is very similar to that of Al. The 71Ga NMR line at 193 ppm observed here remained invisible in previous NMR studies that were carrie...
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Rettenwander D. et al. Site Occupation of Ga and Al in Stabilized Cubic Li7–3(x+y)GaxAlyLa3Zr2O12 Garnets As Deduced from 27Al and 71Ga MAS NMR at Ultrahigh Magnetic Fields // Chemistry of Materials. 2015. Vol. 27. No. 8. pp. 3135-3142.
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Rettenwander D., Langer J., Schmidt W., Arrer C., Harris K. J., Terskikh V., Goward G. R., Wilkening M., Amthauer G. Site Occupation of Ga and Al in Stabilized Cubic Li7–3(x+y)GaxAlyLa3Zr2O12 Garnets As Deduced from 27Al and 71Ga MAS NMR at Ultrahigh Magnetic Fields // Chemistry of Materials. 2015. Vol. 27. No. 8. pp. 3135-3142.
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TY - JOUR
DO - 10.1021/acs.chemmater.5b00684
UR - https://doi.org/10.1021/acs.chemmater.5b00684
TI - Site Occupation of Ga and Al in Stabilized Cubic Li7–3(x+y)GaxAlyLa3Zr2O12 Garnets As Deduced from 27Al and 71Ga MAS NMR at Ultrahigh Magnetic Fields
T2 - Chemistry of Materials
AU - Langer, Julia
AU - Schmidt, Walter
AU - Arrer, Christian
AU - Rettenwander, Daniel
AU - Harris, Kristopher J.
AU - Terskikh, Victor
AU - Goward, Gillian R.
AU - Wilkening, Martin
AU - Amthauer, G.
PY - 2015
DA - 2015/04/14 00:00:00
PB - American Chemical Society (ACS)
SP - 3135-3142
IS - 8
VL - 27
SN - 0897-4756
SN - 1520-5002
ER -
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@article{2015_Rettenwander,
author = {Julia Langer and Walter Schmidt and Christian Arrer and Daniel Rettenwander and Kristopher J. Harris and Victor Terskikh and Gillian R. Goward and Martin Wilkening and G. Amthauer},
title = {Site Occupation of Ga and Al in Stabilized Cubic Li7–3(x+y)GaxAlyLa3Zr2O12 Garnets As Deduced from 27Al and 71Ga MAS NMR at Ultrahigh Magnetic Fields},
journal = {Chemistry of Materials},
year = {2015},
volume = {27},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/acs.chemmater.5b00684},
number = {8},
pages = {3135--3142},
doi = {10.1021/acs.chemmater.5b00684}
}
Cite this
MLA
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Rettenwander, Daniel, et al. “Site Occupation of Ga and Al in Stabilized Cubic Li7–3(x+y)GaxAlyLa3Zr2O12 Garnets As Deduced from 27Al and 71Ga MAS NMR at Ultrahigh Magnetic Fields.” Chemistry of Materials, vol. 27, no. 8, Apr. 2015, pp. 3135-3142. https://doi.org/10.1021/acs.chemmater.5b00684.