Stable Interface Formation between TiS2 and LiBH4 in Bulk-Type All-Solid-State Lithium Batteries
Atsushi Unemoto
1
,
Tamio Ikeshoji
1, 2
,
Syun Yasaku
2
,
Motoaki Matsuo
2
,
Vitalie Stavila
3
,
Terrence John Udovic
4
,
Shin-ichi Orimo
1, 2
2
Publication type: Journal Article
Publication date: 2015-07-28
scimago Q1
wos Q1
SJR: 2.065
CiteScore: 12.0
Impact factor: 7.0
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
In this study, we assembled a bulk-type all-solid-state battery comprised of a TiS2 positive electrode, LiBH4 electrolyte, and Li negative electrode. Our battery retained high capacity over 300 discharge–charge cycles when operated at 393 K and 0.2 C. The second discharge capacity was as high as 205 mAh g–1, corresponding to a TiS2 utilization ratio of 85%. The 300th discharge capacity remained as high as 180 mAh g–1 with nearly 100% Coulombic efficiency from the second cycle. Negligible impact of the exposure of LiBH4 to atmospheric-pressure oxygen on battery cycle life was also confirmed. To investigate the origin of the cycle durability for this bulk-type all-solid-state TiS2/Li battery, electrochemical measurements, thermogravimetry coupled with gas composition analysis, powder X-ray diffraction measurements, and first-principles molecular dynamics simulations were carried out. Chemical and/or electrochemical oxidation of LiBH4 occurred at the TiS2 surface at the battery operating temperature of 393 K...
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135
Total citations:
135
Citations from 2024:
26
(19%)
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GOST
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Unemoto A. et al. Stable Interface Formation between TiS2 and LiBH4 in Bulk-Type All-Solid-State Lithium Batteries // Chemistry of Materials. 2015. Vol. 27. No. 15. pp. 5407-5416.
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Unemoto A., Ikeshoji T., Yasaku S., Matsuo M., Stavila V., Udovic T. J., Orimo S. Stable Interface Formation between TiS2 and LiBH4 in Bulk-Type All-Solid-State Lithium Batteries // Chemistry of Materials. 2015. Vol. 27. No. 15. pp. 5407-5416.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.chemmater.5b02110
UR - https://doi.org/10.1021/acs.chemmater.5b02110
TI - Stable Interface Formation between TiS2 and LiBH4 in Bulk-Type All-Solid-State Lithium Batteries
T2 - Chemistry of Materials
AU - Unemoto, Atsushi
AU - Ikeshoji, Tamio
AU - Yasaku, Syun
AU - Matsuo, Motoaki
AU - Stavila, Vitalie
AU - Udovic, Terrence John
AU - Orimo, Shin-ichi
PY - 2015
DA - 2015/07/28
PB - American Chemical Society (ACS)
SP - 5407-5416
IS - 15
VL - 27
SN - 0897-4756
SN - 1520-5002
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Unemoto,
author = {Atsushi Unemoto and Tamio Ikeshoji and Syun Yasaku and Motoaki Matsuo and Vitalie Stavila and Terrence John Udovic and Shin-ichi Orimo},
title = {Stable Interface Formation between TiS2 and LiBH4 in Bulk-Type All-Solid-State Lithium Batteries},
journal = {Chemistry of Materials},
year = {2015},
volume = {27},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/acs.chemmater.5b02110},
number = {15},
pages = {5407--5416},
doi = {10.1021/acs.chemmater.5b02110}
}
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MLA
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Unemoto, Atsushi, et al. “Stable Interface Formation between TiS2 and LiBH4 in Bulk-Type All-Solid-State Lithium Batteries.” Chemistry of Materials, vol. 27, no. 15, Jul. 2015, pp. 5407-5416. https://doi.org/10.1021/acs.chemmater.5b02110.
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