Light Hydrocarbon Adsorption Mechanisms in Two Calcium-Based Microporous Metal Organic Frameworks
A. M. Plonka
1
,
Xianyin Chen
2
,
Hong Wang
3
,
Rajamani Krishna
4
,
Xing-Long Dong
5
,
Debasis Banerjee
3
,
William R. Woerner
1
,
Yu Han
5
,
Jing Li
3
,
J. B. Parise
1, 2, 6
Publication type: Journal Article
Publication date: 2016-03-01
scimago Q1
wos Q1
SJR: 2.065
CiteScore: 12.0
Impact factor: 7.0
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
The adsorption mechanism of ethane, ethylene, and acetylene (C2Hn; n = 2, 4, 6) on two microporous metal organic frameworks (MOFs) is described here that is consistent with observations from single crystal and powder X-ray diffraction, calorimetric measurements, and gas adsorption isotherm measurements. Two calcium-based MOFs, designated as SBMOF-1 and SBMOF-2 (SB: Stony Brook), form three-dimensional frameworks with one-dimensional open channels. As determined from single crystal diffraction experiments, channel geometries of both SBMOF-1 and SBMOF-2 provide multiple adsorption sites for hydrocarbon molecules through C–H···π and C–H···O interactions, similarly to interactions in the molecular and protein crystals. Both materials selectively adsorb C2 hydrocarbon gases over methane as determined with IAST and breakthrough calculations as well as experimental breakthrough measurements, with C2H6/CH4 selectivity as high as 74 in SBMOF-1.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
3
4
5
6
7
|
|
|
Inorganic Chemistry
7 publications, 6.73%
|
|
|
ACS applied materials & interfaces
5 publications, 4.81%
|
|
|
Industrial & Engineering Chemistry Research
5 publications, 4.81%
|
|
|
Inorganic Chemistry Frontiers
5 publications, 4.81%
|
|
|
Separation and Purification Technology
5 publications, 4.81%
|
|
|
Journal of Materials Chemistry A
5 publications, 4.81%
|
|
|
Dalton Transactions
4 publications, 3.85%
|
|
|
Chemical Engineering Journal
3 publications, 2.88%
|
|
|
Angewandte Chemie - International Edition
3 publications, 2.88%
|
|
|
Angewandte Chemie
3 publications, 2.88%
|
|
|
Energy and Environmental Science
3 publications, 2.88%
|
|
|
Advanced Materials
2 publications, 1.92%
|
|
|
Nature Communications
2 publications, 1.92%
|
|
|
Applied Surface Science
2 publications, 1.92%
|
|
|
Coordination Chemistry Reviews
2 publications, 1.92%
|
|
|
Journal of Environmental Chemical Engineering
2 publications, 1.92%
|
|
|
Chemistry - A European Journal
2 publications, 1.92%
|
|
|
Journal of the American Chemical Society
2 publications, 1.92%
|
|
|
Molecules
2 publications, 1.92%
|
|
|
Journal of Physical Chemistry C
2 publications, 1.92%
|
|
|
Chemical Communications
2 publications, 1.92%
|
|
|
CrystEngComm
2 publications, 1.92%
|
|
|
Microporous and Mesoporous Materials
2 publications, 1.92%
|
|
|
Crystals
1 publication, 0.96%
|
|
|
Science China Chemistry
1 publication, 0.96%
|
|
|
Chinese Journal of Chemical Engineering
1 publication, 0.96%
|
|
|
Water Research
1 publication, 0.96%
|
|
|
Engineering
1 publication, 0.96%
|
|
|
Nano Research
1 publication, 0.96%
|
|
|
Journal of Molecular Catalysis A Chemical
1 publication, 0.96%
|
|
|
1
2
3
4
5
6
7
|
Publishers
|
5
10
15
20
25
30
|
|
|
Elsevier
29 publications, 27.88%
|
|
|
Royal Society of Chemistry (RSC)
24 publications, 23.08%
|
|
|
American Chemical Society (ACS)
23 publications, 22.12%
|
|
|
Wiley
15 publications, 14.42%
|
|
|
Springer Nature
5 publications, 4.81%
|
|
|
MDPI
3 publications, 2.88%
|
|
|
Cambridge University Press
1 publication, 0.96%
|
|
|
OOO Zhurnal "Mendeleevskie Soobshcheniya"
1 publication, 0.96%
|
|
|
AIP Publishing
1 publication, 0.96%
|
|
|
The Russian Academy of Sciences
1 publication, 0.96%
|
|
|
Pleiades Publishing
1 publication, 0.96%
|
|
|
5
10
15
20
25
30
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
104
Total citations:
104
Citations from 2025:
11
(10.58%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Plonka A. M. et al. Light Hydrocarbon Adsorption Mechanisms in Two Calcium-Based Microporous Metal Organic Frameworks // Chemistry of Materials. 2016. Vol. 28. No. 6. pp. 1636-1646.
GOST all authors (up to 50)
Copy
Plonka A. M., Chen X., Wang H., Krishna R., Dong X., Banerjee D., Woerner W. R., Han Yu., Li J., Parise J. B. Light Hydrocarbon Adsorption Mechanisms in Two Calcium-Based Microporous Metal Organic Frameworks // Chemistry of Materials. 2016. Vol. 28. No. 6. pp. 1636-1646.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.chemmater.5b03792
UR - https://doi.org/10.1021/acs.chemmater.5b03792
TI - Light Hydrocarbon Adsorption Mechanisms in Two Calcium-Based Microporous Metal Organic Frameworks
T2 - Chemistry of Materials
AU - Plonka, A. M.
AU - Chen, Xianyin
AU - Wang, Hong
AU - Krishna, Rajamani
AU - Dong, Xing-Long
AU - Banerjee, Debasis
AU - Woerner, William R.
AU - Han, Yu
AU - Li, Jing
AU - Parise, J. B.
PY - 2016
DA - 2016/03/01
PB - American Chemical Society (ACS)
SP - 1636-1646
IS - 6
VL - 28
SN - 0897-4756
SN - 1520-5002
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2016_Plonka,
author = {A. M. Plonka and Xianyin Chen and Hong Wang and Rajamani Krishna and Xing-Long Dong and Debasis Banerjee and William R. Woerner and Yu Han and Jing Li and J. B. Parise},
title = {Light Hydrocarbon Adsorption Mechanisms in Two Calcium-Based Microporous Metal Organic Frameworks},
journal = {Chemistry of Materials},
year = {2016},
volume = {28},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acs.chemmater.5b03792},
number = {6},
pages = {1636--1646},
doi = {10.1021/acs.chemmater.5b03792}
}
Cite this
MLA
Copy
Plonka, A. M., et al. “Light Hydrocarbon Adsorption Mechanisms in Two Calcium-Based Microporous Metal Organic Frameworks.” Chemistry of Materials, vol. 28, no. 6, Mar. 2016, pp. 1636-1646. https://doi.org/10.1021/acs.chemmater.5b03792.