Ligand-Induced Shape Transformation of PbSe Nanocrystals
Publication type: Journal Article
Publication date: 2017-04-19
scimago Q1
wos Q1
SJR: 2.065
CiteScore: 12.0
Impact factor: 7.0
ISSN: 08974756, 15205002
PubMed ID:
28503030
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
We present a study of the relation between the surface chemistry and nanocrystal shape of PbSe nanocrystals with a variable Pb-to-Se stoichiometry and density of oleate ligands. The oleate ligand density and binding configuration are monitored by nuclear magnetic resonance and Fourier transform infrared absorbance spectroscopy, allowing us to quantify the number of surface-attached ligands per NC and the nature of the surface-Pb-oleate configuration. The three-dimensional shape of the PbSe nanocrystals is obtained from high-angle annular dark field scanning transmission electron microscopy combined with an atom counting method. We show that the enhanced oleate capping results in a stabilization and extension of the {111} facets, and a crystal shape transformation from a truncated nanocube to a truncated octahedron.
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Metrics
52
Total citations:
52
Citations from 2024:
8
(15%)
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GOST
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Peters A. L. et al. Ligand-Induced Shape Transformation of PbSe Nanocrystals // Chemistry of Materials. 2017. Vol. 29. No. 9. pp. 4122-4128.
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Peters A. L., van den Bos K. H., Van Aert S., Goris B., Bals S., Vanmaekelbergh D. Ligand-Induced Shape Transformation of PbSe Nanocrystals // Chemistry of Materials. 2017. Vol. 29. No. 9. pp. 4122-4128.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.chemmater.7b01103
UR - https://doi.org/10.1021/acs.chemmater.7b01103
TI - Ligand-Induced Shape Transformation of PbSe Nanocrystals
T2 - Chemistry of Materials
AU - Peters, Anna L
AU - van den Bos, Karel H. W.
AU - Van Aert, Sandra
AU - Goris, Bart
AU - Bals, Sara
AU - Vanmaekelbergh, Daniel
PY - 2017
DA - 2017/04/19
PB - American Chemical Society (ACS)
SP - 4122-4128
IS - 9
VL - 29
PMID - 28503030
SN - 0897-4756
SN - 1520-5002
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2017_Peters,
author = {Anna L Peters and Karel H. W. van den Bos and Sandra Van Aert and Bart Goris and Sara Bals and Daniel Vanmaekelbergh},
title = {Ligand-Induced Shape Transformation of PbSe Nanocrystals},
journal = {Chemistry of Materials},
year = {2017},
volume = {29},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/acs.chemmater.7b01103},
number = {9},
pages = {4122--4128},
doi = {10.1021/acs.chemmater.7b01103}
}
Cite this
MLA
Copy
Peters, Anna L., et al. “Ligand-Induced Shape Transformation of PbSe Nanocrystals.” Chemistry of Materials, vol. 29, no. 9, Apr. 2017, pp. 4122-4128. https://doi.org/10.1021/acs.chemmater.7b01103.